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Transport of BTEX Vapours Through Granular Soils with Different Moisture Contents in the Vadose Zone

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Abstract

The single-ring aromatic hydrocarbons benzene, toluene, ethylbenzene and m-xylene (BTEX) are common and dangerous pollutants in subsurface environments. The diffusive transport of BTEX vapours through the unsaturated zone of the ground is a potential health hazard to humans, living in the vicinity of petroleum fuel contaminated sites. Past studies have shown that gas transport through the vadose zone can be influenced by moisture content due to variations in gaseous permeability, phase partitioning and aerobic biodegradation. In this particular study laboratory soil column experiments were employed to compare the diffusive transport of BTEX vapours through a sand layer of high moisture content, where biodegradation of BTEX compounds occurred, with diffusion through air-dried sand. The presence of a thin soil layer of high moisture content reduced the gaseous concentrations of benzene and toluene and stopped the migration of ethylbenzene and m-xylene vapours, demonstrating its efficiency as a barrier on the diffusive transport of BTEX vapours in unsaturated soil.

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References

  • American Chemical Society (1955) Physical properties of chemical compounds. Advances in chemistry series, vol 15. American Chemical Society, N. W. Washington, DC

    Google Scholar 

  • American Society for Testing and Materials (ASTM) International (2002) ASTM E 1739-95 (2002), Standard guide for risk-based corrective action applied at petroleum release sites. West Conshohocken, PA, ISBN 0-8031-4058-4

  • Batterman S, Kulshrestha A, Cheng HY (1995) Hydrocarbon vapor transport in low moisture soils. Environ Sci Technol 29(1):171–180

    Article  Google Scholar 

  • Christophersen M, Broholm MM, Mosbaek H, Karapanagioti HK, Burganos VN, Kjeldsen P (2005) Transport of hydrocarbons from an emplaced fuel source experiment in the vadose zone at airbase Vaerlose, Denmark. J Contam Hydrol 81:1–33

    Article  Google Scholar 

  • Corley TL, Farrell J, Hong B, Conklin MH (1996) VOC accumulation and pore filling in unsaturated porous media. Environ Sci Technol 30(10):2884–2891

    Article  Google Scholar 

  • Department for Environment Food and Rural Affairs and the Environment Agency (2002a) R & D Publication CLR 7, Assessment of risks to human health from land contamination: an overview of the development of soil guideline values and the related research. Environment Agency, Bristol, UK, 32 pp, ISBN 1 857 05732 5

  • Department for Environment Food and Rural Affairs and the Environment Agency (2002b) R & D Publication CLR 8, Potential contaminants for the assessment of land. Environment Agency, Bristol, UK, 28 pp, ISBN 1 857 05733 3

  • Department for Environment Food and Rural Affairs and the Environment Agency (2002c) R & D Publication CLR 9, Contaminants in soil: collation of toxicological data and intake values for humans. Environment Agency, Bristol, UK, 42 pp, ISBN 1 857 05734 1

  • Department for Environment Food and Rural Affairs and the Environment Agency (2002d) R & D Publication CLR 10, The Contaminated Land Exposure Assessment (CLEA) Model: Technical basis and algorithms. Environment Agency, Bristol, UK, 129 pp, ISBN 1 857 05749 X

  • Department for Environment Food and Rural Affairs and the Environment Agency (2004) Science Report SGV 15, Soil guideline values for toluene contamination. Environment Agency, Bristol, UK, 30 pp, ISBN 1 844 32200 9

  • Department for Environment Food and Rural Affairs and the Environment Agency (2005) Science Report SGV 16, Soil guideline values for ethylbenzene contamination. Environment Agency, Bristol, UK, 29 pp, ISBN 1 844 32199 1

  • Health and Safety Executive (2002) EH40/2002, Occupational exposure limits 2002. Her Majesty’s Stationary Office, Norwich, UK, 106 pp, ISBN 0 7176 2083 2

  • Hers I, Zapf-Gilje R, Li L, Atwater J (2000) Measurement of in situ gas-phase diffusion coefficients. Environ Technol 21:631–640

    Article  Google Scholar 

  • Hohener P, Duwig C, Pasteris G, Kaufmann K, Dakhel N, Harms H (2003) Biodegradation of petroleum hydrocarbon vapours: laboratory studies on rates and kinetics in unsaturated alluvial sand. J Contam Hydrol 66:93–115

    Article  Google Scholar 

  • Jin Y, Streck T, Jury WA (1994) Transport and biodegradation of toluene in unsaturated soil. J Contam Hydrol 17:111–127

    Article  Google Scholar 

  • Johnson PC, Ettinger RA (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings. Environ Sci Technol 25(8):1445–1452

    Article  Google Scholar 

  • Jury WA, Russo D, Streile G, Abd HE (1990) Evaluation of volatilisation by organic chemicals residing below the soil surface. Water Resour Res 26(1):13–20

    Google Scholar 

  • Kim H, Annable MD, Rao PSC (2001) Gaseous transport of volatile organic chemicals in unsaturated porous media: effect of water-partitioning and air–water interfacial adsorption. Environ Sci Technol 35(22):4457–4462

    Article  Google Scholar 

  • Lahvis MA, Baehr AL, Baker RJ (1999) Quantification of aerobic biodegradation and volatilization rates of gasoline hydrocarbons near the water table under natural attenuation conditions. Water Resour Res 35(3):753–765

    Article  Google Scholar 

  • Li C, Voudrias EA (1994a) Migration and sorption of jet fuel aliphatic vapors in unsaturated soil. Water Res 28(12):2447–2456

    Article  Google Scholar 

  • Li C, Voudrias EA (1994b) Migration and sorption of jet fuel cycloalkane and aromatic vapors in unsaturated soil. Environ Prog 13(4):290–297

    Google Scholar 

  • Maier RM, Pepper IL, Gerba CP (2000) Environmental microbiology. Academic Press, San Diego, CA, 585 pp, ISBN 0-12-497570-4

  • Millington RJ, Quirk JP (1961) Permeability of porous solids. Trans Faraday Soc 57:1200–1207

    Article  Google Scholar 

  • Moldrup P, Olesen T, Gamst J, Schjonning P, Yamaguchi T, Rolston DE (2000) Predicting the gas diffusion coefficient in repacked soil: water-induced linear reduction model. Soil Sci Soc Am J 64(5):1588–1594

    Article  Google Scholar 

  • Moldrup P, Olesen T, Komatsu T, Schjonning P, Rolston DE (2001) Tortuosity, diffusivity, and permeability in the soil liquid and gaseous phases. Soil Sci Soc Am J 65(3):613–623

    Google Scholar 

  • Ostendorf DW, Kampbell DH (1991) Biodegradation of hydrocarbon vapors in the unsaturated zone. Water Resour Res 27(4):453–462

    Article  Google Scholar 

  • Ostendorf DW, Hinlein ES, Lutenegger AJ, Kelley SP (2000) Soil gas transport above a jet fuel/solvent spill at Plattsburgh Air Force Base. Water Resour Res 36(9):2531–2547

    Article  Google Scholar 

  • Pankow JF, Cherry JA (1996) Dense chlorinated solvents and other DNAPLs in groundwater. Waterloo Press, Portland, OR, 522 pp, ISBN 0-9648014-1-8

  • Pasteris G, Werner D, Kaufmann K, Hohener P (2002) Vapour phase transport and biodegradation of volatile fuel compounds in the unsaturated zone: a large scale lysimeter experiment. Environ Sci Technol 36(1):30–39

    Article  Google Scholar 

  • Penman HL (1940) Gas and vapour movements in the soil: I. The diffusion of vapours through porous solids. J Agric Sci 30(03):437–462

    Article  Google Scholar 

  • Potter TL, Simmons KE (1998) Total petroleum hydrocarbon criteria working group series, volume 2: composition of petroleum mixtures. Amherst Scientific Publishers, Amherst, MA, 102 pp, ISBN 1-884-940-19-6

  • Shoemaker CA, Culver TB, Lion LW, Peterson MG (1990) Analytical models of the impact of two-phase sorption on subsurface transport of volatile chemicals. Water Resour Res 26(4):745–758

    Google Scholar 

  • U.S. Environmental Protection Agency (2003) U.S. EPA Method 8000C, Determinative chromatographic separations. U.S. EPA, Washington, DC, 66 pp, Revision 3

  • Venkatraman SN, Kosson DS, Schuring JR (1998) Transport and biological fate of toluene in low-permeability soils. Ground Water Monit Remediation 18(1):105–113

    Article  Google Scholar 

  • Wang G, Reckhorn SBF, Grathwohl P (2003) Volatile organic compounds volatilization from multicomponent organic liquids and diffusion in unsaturated porous media. Vadose Zone J 2:692–701

    Article  Google Scholar 

  • Weerts AH, Kandhai D, Bouten W, Sloot PMA (2001) Tortuosity of an unsaturated sandy soil estimated using gas diffusion and bulk soil electrical conductivity: comparing analogy-based models and Lattice-Boltzman simulations. Soil Sci Soc Am J 65(6):1577–1584

    Article  Google Scholar 

  • Wiedemeier TH, Rifai HS, Newell CJ, Wilson JT (1999) Natural attenuation of fuels and chlorinated solvents in the subsurface. Wiley, New York, 617 pp, ISBN 0-471-19749-1

  • World Health Organization (2004) Guidelines for drinking-water quality: 1 recommendations. World Health Organization, Geneva, Switzerland, 515 pp, ISBN 92 4 154638 7

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  1. Panagiotis C. Nerantzis

    Present address: , Paulou Mela 3, P.C. 62123, Serres, Greece

Authors and Affiliations

  1. Department of Civil Engineering, University of Strathclyde, Glasgow, UK

    Panagiotis C. Nerantzis

  2. School of Engineering, Trinity College, Dublin, Ireland

    Mark R. Dyer

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Correspondence to Panagiotis C. Nerantzis.

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Nerantzis, P.C., Dyer, M.R. Transport of BTEX Vapours Through Granular Soils with Different Moisture Contents in the Vadose Zone. Geotech Geol Eng 28, 1–13 (2010). https://doi.org/10.1007/s10706-009-9272-1

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  • DOI: https://doi.org/10.1007/s10706-009-9272-1

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