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Fluorine contamination in groundwater: a major challenge

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A Commentary to this article was published on 19 November 2013

Abstract

Fluoride in high concentration in groundwater has been reported from many parts of India. However, a systematic study is required to understand the behavior of fluoride in natural water in terms of local hydrogeological setting, climatic conditions, and agricultural practices. The present study is an attempt to assess hydrogeochemistry of groundwater in parts of Palar river basin pertaining to Kancheepuram district Tamil Nadu to understand the fluoride abundance in groundwater and to deduce the chemical parameters responsible for the dissolution activity of fluoride. The study area is geologically occupied by partly sedimentary and partly crystalline formations. A total of 50 dug cum borewell-water samples, representing an area of 2,628.92 km2. The results of the chemical analyses in September 2009 show fluoride abundance in the range of 1 to 3.24 mg/l with 86% of the samples in excess of the permissible limit of 1.5 mg/l. Presence of fluoride-bearing minerals in the host rock, chemical properties like decomposition, dissociation, and dissolution, and their interaction with water are considered to be the main causes for fluoride in groundwater. Chemical weathering with relatively high alkalinity favors high concentration of fluoride in groundwater. Villagers who consume nonpotable high fluoride water may suffer from yellow, cracked teeth; joint pains; and crippled limbs and also age rapidly.

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References

  • Apambire, W. B., Boyle, D. R., & Michel, F. A. (1997). Geochemistry, genesis and health implications of fluoriferous ground waters in the upper regions of Ghana. Environmental Geology, 33, 13–24.

    Article  CAS  Google Scholar 

  • Apparao, B. V., & Karthikeyan, G. (1986). Permissible limits of fluoride ion in drinking water in Indian rural environment. Indian Journal of Environmental Protection, 6, 172–175.

    CAS  Google Scholar 

  • BIS (1991). Drinking water specifications: First revision, IS: 10500: 1991.

  • Boyle, D. R., & Chagnon, M. (1995). An incidence of skeletal fluorosis associated with groundwaters of the Maritime Carboniferous Basin, Gaspe Region, Quebec. Environmental Geochemistry and Health, 17, 5–12.

    Article  CAS  Google Scholar 

  • Brown, D. W., & Roberson, C. E. (1977). Solubility of natural fluorite at 25°C. USGS Journal Research, 5(4), 506–517.

    Google Scholar 

  • Chatterjee, M. K., & Mohabey, N. K. (1998). Potential fluorosis problems around Chandidongri, Madhya Pradesh, India. Environmental Geochemistry and Health, 20, 1–4.

    Article  CAS  Google Scholar 

  • Chinoy, N. J., et al. (1992). Studies on effects of fluoride in 36 villages of Mehsana district, North Gujarat. Fluoride, 25, 101–110.

    Google Scholar 

  • Choubisa, S. L., Sompura, K., Bhatt, S. K., Choubisa, D. K., Pandya, H., Joshi, S. C., et al. (1996). Prevalence of fluorosis in some villages of Dungarpur district of Rajasthan. Indian Journal of Environmental Health, 38, 119–126.

    CAS  Google Scholar 

  • Das, S., Mehta, B. C., Samanta, S. K., Das, P. K., & Srivastava, S. K. (2000). Fluoride hazards in groundwater of Orissa, India. Indian Journal of Environmental Health, 1, 40–46.

    Google Scholar 

  • Deshmukh, A. N., & Chakravarti, P. K. (1995). Hydro-chemical and hydrological impact of natural aquifer recharge of selected fluorosis endemic areas of Chandrapur district. Gondwana Geological Magazine, 9, 169–184.

    Google Scholar 

  • Deshkar, S. M., Deshmukh, A. N., & Vali, S. A. (1999). Safe limit of fluoride content in drinking water in different climatic zones of India. Indian Journal of Environmental Health, 2, 17–20.

    Google Scholar 

  • Gupta, S. C., Rathore, G. S., & Doshi, C. S. (1993). Fluoride distribution in groundwaters of southeastern Rajasthan. Indian Journal of Environmental Health, 35, 97–109.

    Google Scholar 

  • Handa, B. K. (1975). Geochemistry and genesis of fluoride containing groundwater in India. Groundwater, 13, 275–281.

    CAS  Google Scholar 

  • Jacks G., Sharma, V. P., & Sharma, G. K. (1980). Hydrochemical studies, SIDA-assisted groundwater project in Kerala—a report (pp. 1–5).

  • Kullenberg, B., & Sen, G. R. (1973). Fluoride in Baltic. Geochimica et Cosmochimica Acta, 37, 1327–1337.

    Article  CAS  Google Scholar 

  • Kundu, N., Panigrahi, M. K., Tripathy, S., Munshi, S., Powell, M. A., & Hart, B. R. (2001). Geochemical appraisal of fluoride contamination of groundwater in the Nayagarh district of Orissa. Environmental Geology, 41, 451–460.

    Article  CAS  Google Scholar 

  • Muralidharan, D., Nair, A. P., & Satyanarayana, U. (2002). Fluoride in shallow aquifers in Rajgarh Tehsil of Churu District, Rajasthan: An arid environment. Current Science, 83, 699–702.

    CAS  Google Scholar 

  • Nawlakhe, W. G., Lutade, S. L., Patni, P. M., & Deshpande, L. S. (1995). Groundwater quality in Shivpuri district in Madhya Pradesh. Indian Journal of Environmental Health, 37, 278–284.

    CAS  Google Scholar 

  • Periakali, P., Subramaniam, S., Eswaramoorthi, S., Arul, B., Rajeshwara Rao, N., & Sridhar, S. G. D. (2001). Distribution of fluoride in the groundwater of Salem and Namakkal districts, Tamil Nadu. Journal of Applied Geochemistry, 3(2), 120–132.

    Google Scholar 

  • Ramesham, V., & Rajagopalan, K. J. (1985). Fluoride ingestion into the natural water of hard rock areas, Peninsular India. Journal of the Geological Society of India, 26, 125–132.

    Google Scholar 

  • Ramasesha, C. S., Kumar, E. S., Suresh, S., & Kumar, A. R. (2002). Occurrence of nitrate and fluoride in groundwater and their impacts in and around Dindigul, Tamil Nadu, India.

  • Rao, N. S. (2003). Groundwater quality: Focus on fluoride concentration in rural parts of Guntur district, Andhra Pradesh, India. Hydrological Sciences Journal, 48, 35.

    Google Scholar 

  • Rao, N. S., & Devadas, D. J. (2003). Fluoride incidence in groundwater in an area of Peninsular India. Environmental Geology, 45, 243–251.

    Article  CAS  Google Scholar 

  • Ray, D., Rao, R. R., Bhoi, A. V., Biswas, A. K., Ganguly, A. K., & Sanyal, P. I. (2000). Physico-chemical quality of drinking water in Rohtas district of Bihar. Environmental Monitoring and Assessment, 61, 387–398.

    Article  CAS  Google Scholar 

  • Shaji, E., Bindu, J. V., & Thambi, D. S. (2007). High fluoride in groundwater of Palghat District, Kerala. Current Science, 92, 240–245.

    CAS  Google Scholar 

  • Sreedevi, P. D., Ahmed, S., Made, B., Ledoux, E., & Gandolfi, J. M. (2006). Association of hydro-geological factors in temporal variations of fluoride concentration in a crystalline aquifer in India. Environmental Geology, 50, 1–11.

    Article  CAS  Google Scholar 

  • Sumalatha, S., Ambika, S. R. A., & Prasad, S. J. (1999). Fluoride concentration status of groundwater in Karnataka, India. Current Science, 76, 730–734.

    Google Scholar 

  • Susheela, A. K. (1999). Fluorosis management programme in India. Current Science, 77, 1250–1256.

    Google Scholar 

  • Susheela, A. K., Bhatnagar, M., & Kumar, A. (1996). Status of drinking water in the mega city Delhi. In Proceedings of the 22nd WEDC (Water, Environment and Management Conference), New Delhi (pp. 1–3).

  • Wenzel, W. W., & Blum, W. E. H. (1992). Fluoride speciation and mobility in fluoride contaminated soils and minerals. Soil Science, 153, 357–364.

    Article  CAS  Google Scholar 

  • WHO (1984). Guidelines for drinking water quality, values 3; drinking water quality control in small community supplies (212p). Geneva: WHO.

    Google Scholar 

  • Wodeyar, B. K., & Sreenivasan, G. (1996). Occurrence of fluoride in the groundwaters and its impact in Peddavankahalla basin, Bellary District, Karnataka—a preliminary study. Current Science, 70, 71–74.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Industries and Earth Sciences, The Tamil University, Thanjavur, Tamil Nadu, India

    Mithas Ahmad Dar, K. Sankar & Imran A. Dar

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  1. Mithas Ahmad Dar
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  2. K. Sankar
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  3. Imran A. Dar
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Correspondence to Mithas Ahmad Dar.

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A comment to this article is available at http://dx.doi.org/10.1007/s10661-013-3525-4.

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Dar, M.A., Sankar, K. & Dar, I.A. Fluorine contamination in groundwater: a major challenge. Environ Monit Assess 173, 955–968 (2011). https://doi.org/10.1007/s10661-010-1437-0

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