A study was carried out on the behavior of monomeric germylenes derived from pyridine-containing diols in reactions with diphenylphosphoryl azide and 9,10-phenanthrenequinone. It was found that the germanium atom increases its oxidation state to 4+ in these reactions. The structure of the product of the reaction with 9,10-phenanthrenequinone was confirmed by X-ray structural analysis, which showed a transannular germanium-nitrogen interaction in this product.
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*In memoriam Professor Edmunds Lukevics.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1891-1896, December, 2011.
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Huang, M., Kireenko, M.M., Zaitsev, K.V. et al. Germylenes derived from pyridine-containing diols: reactions with diphenylphosphoryl azide and 9,10-phenanthrenequinone*. Chem Heterocycl Comp 47, 1584–1589 (2012). https://doi.org/10.1007/s10593-012-0950-1
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DOI: https://doi.org/10.1007/s10593-012-0950-1