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Synthesis and Characterization of Nickel Metal-Organic Framework Including 4,6-diamino-2-mercaptopyrimidine and its Catalytic Application in Organic Reactions

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Abstract

In this work, 4,6-diamino-2-mercaptopyrimidine was applied as an outstanding chelating agent for the preparation of a novel nickel metal–organic framework (Ni-DAMP-MOF) as a heterogeneous and reusable catalyst. The prepared MOF was characterized by XRD, SEM, EDS, WDX, TGA, BET, FT-IR, and AAS techniques. Subsequently, this metal–organic framework was used as a new catalyst in the synthesis of pyranopyrazoles and selective oxidation of sulfides to sulfoxides. All products were obtained with high purity and excellent yields, which indicate the high catalytic activity of this catalyst. Also, this catalyst was shown a good selectivity in the oxidation of sulfides to sulfoxides. Finally, the reusability of this catalyst was investigated as an important principle in green chemistry.

Graphical Abstract

A new MOFs structure of nickel (Ni-DAMP-MOF) was prepared as an efficient catalyst in the synthesis of pyranopyrazoles and selective oxidation of sulfides to sulfoxides. Ni-DAMP-MOF was characterized by XRD, SEM, EDS, WDX, TGA, BET, FT-IR, and AAS techniques. This catalyst indicated good chemoselectivity in the synthesis of sulfoxides. This catalyst was recovered and recycled several consecutive times.

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Data available in article supplementary material; the data that supports the findings of this study are available in the supplementary material of this article.

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Acknowledgements

The authors thank the research facilities of Ilam University, Ilam, Iran, and Bu-Ali Sina University, Hamedan, Iran for the financial support of this research project.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, P. O. Box 69315516, Ilam, Iran

    Abbas Rezaei & Bahman Tahmasbi

  2. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683, Iran

    Arash Ghorbani-Choghamarani

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  1. Abbas Rezaei
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Correspondence to Arash Ghorbani-Choghamarani or Bahman Tahmasbi.

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Rezaei, A., Ghorbani-Choghamarani, A. & Tahmasbi, B. Synthesis and Characterization of Nickel Metal-Organic Framework Including 4,6-diamino-2-mercaptopyrimidine and its Catalytic Application in Organic Reactions. Catal Lett 153, 2005–2017 (2023). https://doi.org/10.1007/s10562-022-04135-8

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