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Agro-Waste Generated Pd/CAP-Ash Catalyzed Ligand-Free Approach for Suzuki–Miyaura Coupling Reaction

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Abstract

We converted agro-waste Custard Apple Peels (CAP) to ash via thermal treatment, on which Pd(OAc)2 was immobilized easily that produced a low-cost, highly efficient Pd/CAP-ash catalyst. The prepared catalyst was fully characterized by using FT-IR, SEM, EDX, XRF, DSC-TGA, BET, HR-TEM, and XPS techniques. The Pd/CAP-ash catalyst was conveniently applied for the Suzuki–Miyaura coupling reaction under external base free and ligand-free conditions in an aqueous-organic solvent to produce biphenyls in good to excellent yields. The main attraction of our protocol an application of palladium-supported agro-waste material which is easily recoverable and recyclable provides mono and bis-coupled derivatives in a short reaction time.

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Acknowledgements

One of the authors, Rupesh C. Patil is grateful to Chhatrapati Shahu Maharaj Research Training and Human Development Institute (SARTHI), Pune (Government of Maharashtra), India for the award of the CMSRF-2019 fellowship. [CIN-U74999PN2018NPL177394, dated 11th Sept. 2019]

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Authors and Affiliations

  1. Synthetic Research Laboratory, PG Department of Chemistry, PDVP College, (affiliated to Shivaji University, Kolhapur), Tasgaon, Sangli, MS, 416312, India

    Rupesh C. Patil, Ashutosh A. Jagdale, Uttam P. Patil & Suresh S. Patil

  2. Department of Physics, PDVP College, (affiliated to Shivaji University, Kolhapur), Tasgaon, Sangli, MS, 416312, India

    Jeevan S. Ghodake

  3. Polymer Energy Materials Laboratory, School of Advanced Chemical Engineering, Chonnam National University, Gwangju, 500-757, South Korea

    Sawanta S. Mali & Chang K. Hong

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  1. Rupesh C. Patil
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  3. Uttam P. Patil
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Patil, R.C., Jagdale, A.A., Patil, U.P. et al. Agro-Waste Generated Pd/CAP-Ash Catalyzed Ligand-Free Approach for Suzuki–Miyaura Coupling Reaction. Catal Lett 151, 3617–3631 (2021). https://doi.org/10.1007/s10562-021-03597-6

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