Abstract
Nowadays, increasing attention has been focused on tailor-made aerogels through the addition of different components, which have been employed in specific catalytic reactions. In this study, Fe-doped alumina aerogel as a novel heterogeneous catalyst for degradation of Rhodamine B (RhB) was constructed by sol–gel one-step method, which is not only simple, but also can avoid the leaching of active components during degradation of RhB. Besides, the catalyst maintains high activity for the degradation of RhB within a wide range of pH values (2–10). Heat treatment could lead to enhancement of Fe–O–Al bond and significantly inhibit iron leaching. Effects of some parameters, including reaction temperature, dosages of H2O2, pH values and RhB concentrations on RhB degradation were also investigated. FTIR and ICP analysis shows that the catalyst exhibits low iron leaching, good structural stability and high catalytic efficiency after reuse. The catalytic mechanism and RhB degradation pathway were proposed based on the results of electron paramagnetic resonance (EPR) and the liquid chromatography-mass spectrometry (LCMS). We believe that Fe-doped alumina aerogel can be an efficient and green heterogeneous catalyst for the degradation of organic pollutants.
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Martínez-Huitle CA, Brillas E (2015) Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: an updated review. Appl Catal B 166–167:603–643
Li XQ, Zhang QH, Ma K, Li HM, Guo Z (2015) Identification and determination of 34 water-soluble synthetic dyes in foodstuff by high performance liquid chromatography-diode array detection-ion trap time-of-flight tandem mass spectrometry. Food Chem 182:316–326
Natarajan TS, Thomas M, Natarajan K, Bajaj HC, Tayade RJ (2011) Study on UV-LED/TiO2 process for degradation of Rhodamine B dye. Chem Eng J 169:126–134
Amin MT, Alazba AA, Manzoor U (2014) A review of removal of pollutants from water/wastewater using different types of nanomaterials. Adv Mater Sci Eng 2014:1–24
Yin W, Wang W, Zhou L, Sun S, Zhang L (2010) CTAB-assisted synthesis of monoclinic BiVO4 photocatalyst and its highly efficient degradation of organic dye under visible-light irradiation. J Hazard Mater 173:194–199
Merouani S, Hamdaoui O, Saoudi F, Chiha M, Pétrier C (2010) Influence of bicarbonate and carbonate ions on sonochemical degradation of Rhodamine B in aqueous phase. J Hazard Mater 175:593–599
Antonopoulou M, Evgenidou E, Lambropoulou D, Konstantinou I (2014) A review on advanced oxidation processes for the removal of taste and odor compounds from aqueous media. Water Res 5:215–234
Asghar A, Abdul Raman AA, Daud WMAW (2015) Advanced oxidation processes for in situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: a review. J Clean Prod 87:826–838
Chong MN, Sharma AK, Burn S, Saint CP (2012) Feasibility study on the application of advanced oxidation technologies for decentralised wastewater treatment. J Clean Prod 35:230–238
Lim H, Lee J, Jin S, Kim J, Yoon J, Hyeon T (2006) Highly active heterogeneous Fenton catalyst using iron oxide nanoparticles immobilized in alumina coated mesoporous silica. Chem Commun 4:463–465
Yang XJ, Xu XM, Xu J, Han YF (2013) Iron oxychloride (FeOCl): an efficient Fenton-like catalyst for producing hydroxyl radicals in degradation of organic contaminants. J Am Chem Soc 135:16058–16061
Xue X, Hanna K, Deng N (2009) Fenton-like oxidation of Rhodamine B in the presence of two types of iron (II, III) oxide. J Hazard Mater 166:407–414
Fan Y, Ai Z, Zhang L (2010) Design of an electro-Fenton system with a novel sandwich film cathode for wastewater treatment. J Hazard Mater 176:678–684
He J, Tao X, Ma W, Zhao J (2002) Heterogeneous photo-fenton degradation of an azo dye in aqueous H2O2/iron oxide dispersions at neutral phs. Chem Lett 31:86
Anipsitakis GP, Dionysiou DD (2003) Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt. Environ Sci Technol 37:4790–4797
Anipsitakis GP, Dionysiou DD (2003) Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt. Environ Sci Technol 37:4790–4797
Yang Q, Choi H, Al-Abed SR, Dionysiou DD (2009) Iron-cobalt mixed oxide nanocatalysts: heterogeneous peroxymonosulfate activation, cobalt leaching, and ferromagnetic properties for environmental applications. Appl Catal B 88:462–468
Wang Y, Zhao H, Li M, Fan J, Zhao G (2014) Magnetic ordered mesoporous copper ferrite as a heterogeneous Fenton catalyst for the degradation of imidacloprid. Appl Catal B 147:534–545
Ren Y, Dong Q, Feng J, Ma J, Wen Q, Zhang M (2012) Magnetic porous ferrospinel NiFe2O4: a novel ozonation catalyst with strong catalytic property for degradation of di-n-butyl phthalate and convenient separation from water. J Colloid Interface Sci 382:90–96
Fu YS, Chen HQ, Sun XQ, Wang X (2012) Combination of cobalt ferrite and graphene: high-performance and recyclable visible-light photocatalysis. Appl Catal B 111:280–287
Yao YJ, Yang ZH, Zhang DW, Peng WC, Sun HQ, Wang SB (2012) Magnetic CoFe2O4-graphene hybrids: facile synthesis, characterization, and catalytic properties. Ind Eng Chem Res 51:6044–6051
Kadu BS, Limaye RA, Natu AD, Chikate RC (2013) Potentiality of Fe–Ni nanocomposites towards environmental abetment of magenta dye. Environ Prog Sustain Energy 32:615–623
Navalon S, De Miguel M, Martin R, Alvaro M, Garcia H (2011) Enhancement of the catalytic activity of supported gold nanoparticles for the fenton reaction by light. J Am Chem Soc 133:2218–2226
Hu P, Long M, Bai X et al (2017) Monolithic cobalt-doped carbon aerogel for efficient catalytic activation of peroxymonosulfate in water. J Hazard Mater 332:195–204
Hüsing N, Schubert U (1998) Aerogels—airy materials: chemistry, structure, and properties. Angew Chem Int 37:22–45
Maleki H (2016) Recent advances in aerogels for environmental remediation applications: a review. Chem Eng J 300:98–118
Amonette JE, Matyáš J (2017) Functionalized silica aerogels for gas-phase purification, sensing, and catalysis: a review. Microporous Mesoporous, Mat
Dunn BC, Cole P, Covington D, Webster MC, Pugmire RJ, Ernst RD, Eyring EM, Shah N, Huffman GP (2005) Silica aerogel supported catalysts for Fischer-Tropsch synthesis. Appl Catal A 278:233–238
Bali S, Huggins FE, Huffman GP, Ernst RD, Pugmire RJ, Eyring EM (2009) Iron aerogel and xerogel catalysts for Fischer-Tropsch synthesis of diesel fuel. Energy Fuels 23:14–18
Rotter H, Landau MV, Carrera M, Goldfarb D, Herskowitz M (2004) High surface area chromia aerogel efficient catalyst and catalyst support for ethylacetate combustion. Appl Catal B 47:111–126
Maleki H, Hüsing N (2018) Current status, opportunities and challenges in catalytic and photocatalytic applications of aerogels: environmental protection aspects. Appl Catal B 221:530–555
Schwarz JA, Contescu C, Contescu A (1995) Methods for preparation of catalytic materials. Chem Rev 95:477–510
Feinle A, Elsaesser MS, Hüsing N (2016) Sol–gel synthesis of monolithic materials with hierarchical porosity Chem. Soc Rev 45:3377–3399
Gao B, Ma Y, Mei J et al (2018) Functional nanocomposite wet gels and aerogels induced by transition/lanthanide metal ions coordination. Chem Eng J 331:597–605
Ren L, Cui S, Cao F et al (2014) An easy way to prepare monolithic inorganic oxide aerogels. Angew Chem Int 53:10147–10149
Gong C, Chen F, Yang Q et al (2017) Heterogeneous activation of peroxymonosulfate by Fe-Co layered doubled hydroxide for efficient catalytic degradation of Rhoadmine B. Chem Eng J 321:222–232
Adam F, Andas J, Rahman IA (2010) A study on the oxidation of phenol by heterogeneous iron silica catalyst. Chem Eng J 165:658–667
Li Y, Feng Z, Lian Y, Sun K, Zhang L, Jia G, Yang Q, Li C (2005) Direct synthesis of highly ordered Fe-SBA-15 mesoporous materials under weak acidic conditions. Microporous Mesoporous Mater 84:41–49
Xin H, Liu J, Fan F, Feng Z, Jia G, Yang Q, Li C (2008) Mesoporous ferrosilicates with high content of isolated iron species synthesized in mild buffer solution and their catalytic application. Microporous Mesoporous Mater 113:231–239
Li J, Wang J, Zhang G et al (2018) Enhanced molecular oxygen activation of Ni2+-doped BiO2-x nanosheets under UV, visible and near-infrared irradiation: mechanism and DFT study. Appl Catal B 234:167–177
Yamashita T, Hayes P (2008) Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials. Appl Surf Sci 254:2441–2449
Biesinger MC, Payne BP, Grosvenor AP et al (2011) Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl Surf Sci 257:2717–2730
Maldonado CS, De la Rosa J, Lucioortiz CJ et al (2014) Low concentration Fe-doped alumina catalysts using sol-gel and impregnation methods: the synthesis, characterization and catalytic performance during the combustion of trichloroethylene. Materials 7:2062–2086
Cao F, Ren L, Li X (2015) Synthesis of high strength monolithic alumina aerogels at ambient pressure. RSC Adv 5:18025–18028
Gan PP, Li SFY (2013) Efficient removal of Rhodamine B using a rice hull-based silica supported iron catalyst by Fenton-like process. Chem Eng J 229:351–363
Wang K, Li Y, Zhang G et al (2019) 0D Bi nanodots/2D Bi3NbO7 nanosheets heterojunctions for efficient visible light photocatalytic degradation of antibiotics: enhanced molecular oxygen activation and mechanism insight. Appl Catal B 240:39–49
Ramirez JH, Costa CA, Madeira LM, Mata G, Vicente MA, Rojas-Cervantes ML, López-Peinado AJ, Martín-Aranda RM (2007) Fenton-like oxidation of Orange II solutions using heterogeneous catalysts based on saponite clay. Appl Catal B 71:44–56
Yu K, Yang S, Boyd SA, Chen H, Sun C (2011) Efficient degradation of organic dyes by BiAgxOy. J Hazard Mater 197:88–96
Neyens E, Baeyens J (2003) A review of classic Fenton’s peroxidation as an advanced oxidation technique. J Hazard Mater 98:33–50
Liu SQ, Cheng S, Feng LR, Wang XM, Chen Z-G (2010) Effect of alkali cations on heterogeneous photo-Fenton process mediated by Prussian blue colloids. J Hazard Mater 182:665–671
Guo T, Wang K, Zhang G et al (2019) A novel α-Fe2O3@ g-C3N4 catalyst: synthesis derived from Fe-based MOF and its superior photo-Fenton performance. Appl Surf Sci 469:331–339
Biaglow JE, Kachur AV (1997) The generation of hydroxyl radicals in the reaction of molecular oxygen with polyphosphate complexes of ferrous ion. Radiat Res 148:181–187
Dias FF, Oliveira AAS, Arcanjo AP et al (2016) Residue-based iron catalyst for the degradation of textile dye via heterogeneous photo-Fenton. Appl Catal B 186:136–142
Nguyen XS, Zhang G, Yang X (2017) Mesocrystalline Zn-doped Fe3O4 hollow submicrospheres: formation mechanism and enhanced photo-Fenton catalytic performance. ACS Appl. Mater. Interface 9:8900–8909
Acknowledgements
We gratefully acknowledge the financial support of the Nature Science Foundation of Jiangsu Province of China (BK20151408) and the Fundamental Research Funds for the Central Universities (2242016K41018 and KYLX16_0193) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (1107047002) and Graduate Practice Innovation Program of Jiangsu Province of China (SJCX17_0031).
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Mei, J., Yuan, G., Ma, Y. et al. Fe-Doped Alumina Aerogels as a Green Heterogeneous Catalyst for Efficient Degradation of Organic Pollutants. Catal Lett 149, 1874–1887 (2019). https://doi.org/10.1007/s10562-019-02797-5
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DOI: https://doi.org/10.1007/s10562-019-02797-5