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Palladium(II) on Functionalized NiFe2O4: An Efficient and Recyclable Phosphine-Free Heterogeneous Catalyst for Suzuki Coupling Reaction

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Abstract

Superparamagnetic NiFe2O4 catalyst immobilized palladium(II) has been synthesized using a microemulsion method and functionalized with Schiff-base group to form an immobilized bidentate ligand. The catalyst was characterized by multiple analytical techniques. The immobilized palladium complex was used in EtOH/water under aerobic conditions. The catalyst is applicable for various substrates and easily separable. The as-prepared catalyst was reused up to five runs with slight decrease in catalytic activity.

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Acknowledgments

Financial Support from Green Tech. U.P.E. is gratefully acknowledged. The author also thanks Nano Center University of Mumbai for providing XPS facility.

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Authors and Affiliations

  1. Department of Chemistry, Institute of Chemical Technology, Matunga, Mumbai, 400019, India

    Abhilash S. Singh, Radheshyam S. Shelkar & Jayashree M. Nagarkar

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  1. Abhilash S. Singh
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  2. Radheshyam S. Shelkar
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  3. Jayashree M. Nagarkar
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Corresponding author

Correspondence to Jayashree M. Nagarkar.

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Singh, A.S., Shelkar, R.S. & Nagarkar, J.M. Palladium(II) on Functionalized NiFe2O4: An Efficient and Recyclable Phosphine-Free Heterogeneous Catalyst for Suzuki Coupling Reaction. Catal Lett 145, 723–730 (2015). https://doi.org/10.1007/s10562-014-1455-6

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  • DOI: https://doi.org/10.1007/s10562-014-1455-6

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