Abstract
Mo oxide species were prepared on oxide supports and applied for selective photo-oxidation of propane. Mo oxide on mesoporous alumina had a monomeric structure whereas that on mesoporous silica had an oligomeric structure. The main product of the propane photo-oxidation reaction was acetone and propene on Mo oxide monomer unit and on oligomer unit, respectively.
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Acknowledgments
This study was financially supported by Tokuyama Science Foundation. XAFS experiments were performed on the BM23 beamline at the European Synchrotron Radiation Facility (ESRF), Grenoble, France (CH-3497, Priority Program for Disaster-Affected Quantum Beam Facilities) and NW10A beamline at KEK-PF AR, Tsukuba, Japan (2010G064). We are grateful to Dr. Santiago Figueroa at ESRF for providing assistance in using beamline BM23.
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Ichikuni, N., Nakao, Y., Ishizuki, K. et al. Effect of Local Structure of Mo Oxide on Selective Photo-Oxidation of Propane to Acetone. Catal Lett 143, 154–158 (2013). https://doi.org/10.1007/s10562-012-0948-4
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DOI: https://doi.org/10.1007/s10562-012-0948-4