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Dehydrogenation of Cyclohexanol on Fe, Ti-MCM-41 Mesoporous Materials

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Abstract

Iron and titanium modified MCM-41 materials, prepared by direct synthesis were investigated using X-ray diffraction (XRD), nitrogen physisorption, UV–Vis diffuse reflectance, Mössbauer, FT-IR and EPR spectroscopies. Materials with high surface area and well-ordered pore structure were obtained. All modified mesoporous silicas possess high activity in cyclohexanol conversion. FeTiMCM-41 (Si/Ti = 10, Si + Ti/Fe = 15) catalyst presented the highest activity and selectivity to cyclohexanone.

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Acknowledgments

Financial support by the project DO02-295_2008 and the Bulgarian–Hungarian Inter-academic Exchange Agreement are greatly acknowledged.

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Authors and Affiliations

  1. Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev str., bl.9, 1113, Sofia, Bulgaria

    M. Popova

  2. Institute of Nanochemistry and Catalysis, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, Budapest, 1025, Hungary

    Á. Szegedi

  3. Institute of Isotopes, Hungarian Academy of Sciences, PO Box 77, Budapest, 1525, Hungary

    K. Lázár

  4. Institute of Catalysis, Bulgarian Academy of Sciences, 1113, Sofia, Bulgaria

    A. Dimitrova

Authors
  1. M. Popova
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  2. Á. Szegedi
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  3. K. Lázár
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  4. A. Dimitrova
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Correspondence to M. Popova.

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Popova, M., Szegedi, Á., Lázár, K. et al. Dehydrogenation of Cyclohexanol on Fe, Ti-MCM-41 Mesoporous Materials. Catal Lett 141, 1288–1296 (2011). https://doi.org/10.1007/s10562-011-0652-9

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  • DOI: https://doi.org/10.1007/s10562-011-0652-9

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