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Partial Oxidation of Isobutane over Vanadium Phosphorus Oxides

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Abstract

A series of vanadium phosphorus oxides (VPO) were prepared by using dodecyl amine as surfactant and tested for the partial oxidation of isobutane and isobutene. Characterization results showed that their structure and properties depend on the content of dodecyl amine. Catalytic tests showed that relatively high isobutane conversion and desired product selectivity can be achieved over a proper dodecyl amine doping VPO catalyst. It is also found that higher isobutane conversion can be achieved over V4+-containing phases as compared to V5+-containing phases, while proper surface V5+/V4+ ratio may be propitious to obtain high selectivity to methacrylic acid for the selective oxidation of isobutane. In addition, the content of dodecyl amine in the preparation of the VPO catalysts appears to be more important in determining the surface P/V ratio of the catalysts.

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Acknowledgments

We acknowledge the financial supports from the National Basic Research Program of China (2004CB217804) and the National Natural Science Foundation of China (20673046).

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130023, People’s Republic of China

    Jingqi Guan, Zhuqian Wang, Chen Xu, Ying Yang, Bo Liu, Xiaofang Yu & Qiubin Kan

  2. Jiefang road 2519, Changchun, 130021, People’s Republic of China

    Qiubin Kan

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  1. Jingqi Guan
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  2. Zhuqian Wang
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  4. Ying Yang
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Correspondence to Qiubin Kan.

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Guan, J., Wang, Z., Xu, C. et al. Partial Oxidation of Isobutane over Vanadium Phosphorus Oxides. Catal Lett 128, 356–362 (2009). https://doi.org/10.1007/s10562-008-9753-5

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  • DOI: https://doi.org/10.1007/s10562-008-9753-5

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