Skip to main content
SpringerLink
Log in

Approximation of the Separation Boundary in Water-Hydrotrope-Oil Ternary Systems

  • RESEARCH
  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

In this work, we studied the water-2-butoxyethanol-toluene, water-methanol-chloroform, and water-methanol-dichloromethane ternary systems. The position of the separation boundary was experimentally determined and approximated by various functions. We elucidated the major factors hindering satisfactory approximation of separation boundaries by empirical functions with a small number of adjustable parameters. The approximation of separation boundaries in ternary systems can be carried out using polynomial and smoothing spline functions with error comparable to experimental uncertainty.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. D. Subramanian et al., Faraday Discuss., 167, 217 (2013).

    Article  Google Scholar 

  2. A. A. Novikov et al., J. Phys. Chem. C, 121, No. 30, 16423-16431 (2017).

    Article  CAS  Google Scholar 

  3. A. P. Semenov, et al., Chem. Technol. Fuels Oils, 52, No. 2, 162-170 (2016).

    Article  CAS  Google Scholar 

  4. A. P. Semenov, et al., J. Chem. Thermodyn., 137, 119-130 (2019).

    Article  CAS  Google Scholar 

  5. A. P. Semenov, et al., Chem. Technol. Fuels Oils, 54, No. 6, 738-742 (2019).

    Article  CAS  Google Scholar 

  6. J. M. Cohen, P. F. Wolf, and W. D. Young, Energy & Fuels, 12, No. 2, 216-218 (1998).

    Article  CAS  Google Scholar 

  7. F. T. Reyes and M. A. Kelland, Energy & Fuels, 27, No. 3, 1314-1320 (2013).

    Article  CAS  Google Scholar 

  8. M. Lotti, et al., Biotechnol. J., 10, No. 1, 22-30 (2015).

    Article  CAS  Google Scholar 

  9. N. R. Al’myasheva, et al., Chem. Technol. Fuels Oils, 50, No. 6, 449-452 (2015).

    Article  Google Scholar 

  10. W. B. Driskell and J. R. Payne, Mar. Pollut. Bull., 129 , No. 1, 412-419 (2018).

    Article  CAS  Google Scholar 

  11. Z. Cai, et al., Mar. Pollut. Bull., 114, No. 1, 408-418 (2017).

    Article  CAS  Google Scholar 

  12. S. R. Kline and E. W. Kaler, Langmuir, 10, No. 2, 412-417 (1994).

    Article  CAS  Google Scholar 

  13. A. A. Novikov, et al., Langmuir, 35, No. 41, 13480-13487 (2019).

    Article  CAS  Google Scholar 

  14. T. M. Letcher, S. Ravindran, and S. E. Redloff, Fluid Phase Equilib., 69, 251-260 (1991).

    Article  CAS  Google Scholar 

  15. A. K. Wyczalkowska, J. Sengers, and M. Anisimov, Phys. A Stat. Mech. Its Appl., 334, Nos. 3-4, 482-512 (2004).

    Article  Google Scholar 

  16. A. W. Francis, J. Phys. Chem., 62, No. 5, 579-584 (1958).

    Article  CAS  Google Scholar 

Download references

The research is supported by the Russian Science Foundation (Grant No. 20-79-10388).

Author information

Authors and Affiliations

  1. Gubkin University, Moscow, Russia

    A. A. Kuchierskaya, A. V. Diyakovskaya, A. R. Sayfutdinova, A. P. Semenov & A. A. Novikov

Authors
  1. A. A. Kuchierskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Diyakovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. R. Sayfutdinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. P. Semenov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Novikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Novikov.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 5, pp. 20–22, September-October, 2021.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kuchierskaya, A.A., Diyakovskaya, A.V., Sayfutdinova, A.R. et al. Approximation of the Separation Boundary in Water-Hydrotrope-Oil Ternary Systems. Chem Technol Fuels Oils 57, 753–757 (2021). https://doi.org/10.1007/s10553-021-01302-2

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10553-021-01302-2

Keywords

Search

Navigation