Skip to main content
Log in

Morphology and activity of multicomponent heterogeneous catalysts by binary cuts

  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

Abstract

In oxidation of carbon monoxide, the activity of the Cu-Cr-Mn/γ-Al2O3 catalytic system is correlated with its morphology. The phase composition and valence state of the metal ions in catalysts of different genesis were investigated by x-ray phase analysis (XPA) and diffuse-reflection electron spectroscopy (DRES). The sequence of application of the active components of the system over binary sections affects the catalytic activity. The undesirable copper-chromium combination is excluded by separation of the successively applied combinations of ingredients Cr-Cu and Cu- Mn through an intermediate stage.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. R. R. Aliev, B. Z. Solyar, A. F. Babikov, et al., Khim. Tekhnol. Topl. Masel, No. 4, 21–23 (1995).

  2. R. M. Talyshinskii, M. K. Guseinova, and N. M. Mardanova, Kinet. Katal., No. 4, 933–973 (1987).

  3. Yu. A. Panteleeva, A. M. Musaev, and R. M. Talyshinskii, Ibid., 32, No.3, 642–646 (1991).

    Google Scholar 

  4. L. I. Kheifets and A. V. Neimark, Multiphase Processes in Porous Media [in Russian], Khimiya, Moscow (1982).

    Google Scholar 

  5. N. M. Mardanova, R. B. Akhverdiev, R. M. Talyshinskii, et al., Kinet. Katal., 37, No.1, 90–95 (1996).

    Google Scholar 

  6. N. M. Mardanova, Sh. Sh. Suleimanov, R. M. Talyshinskii, et al., Ibid., 96–103.

  7. N. I. Koltsov, V. Kh. Fedotov, and B. V. Alekseev, in: Proceedings of the All-Union Conference on the Mechanism of Catalytic Reactions [in Russian], Part 2, Khimiya, Moscow (1986), p. 430.

    Google Scholar 

  8. S. A. Dorofeev, G. T. Farkhadova, V. S. Gadzhi-Kasumov, et al., in: Proceedings of the Republic Scientific and Technical Conference on Catalytic Cracking, October 25–27, 1988, Baku [in Russian], ELM, Baku (1989), pp, 51–52.

    Google Scholar 

  9. M. I. Rustamov, A. M. Guseinov, A. A. Mkrtychev, et al., Khim. Tekhnol. Topl. Masel, No. 4, 20–22 (1988).

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 1, pp. 40 – 42, January – February, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Talyshinskii, R.M., Aliev, R.R. & Mkrtychev, A.A. Morphology and activity of multicomponent heterogeneous catalysts by binary cuts. Chem Technol Fuels Oils 41, 60–65 (2005). https://doi.org/10.1007/s10553-005-0022-7

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10553-005-0022-7

Key words

Navigation