Skip to main content
Log in

Essential and Non-essential Work of Fracture of PI/SiO2 Hybrid Thin Films

  • Published:
Applied Composite Materials Aims and scope Submit manuscript

Abstract

Essential work of fracture (EWF) analysis is used to study the effect of the silica doping level on fracture toughness of polyimide/silica (PI/SiO2) hybrid films. By using double-edge-notched-tension (DENT) specimens with different ligament lengths, it seems that the introduction of silica additive can improve the specific essential work of fracture (w e ) of PI thin films, but the specific non-essential work of fracture (βw p ) will decease significantly as the silica doping level increasing from 1 to 5 wt.%, and even lower than that of neat PI. The failure process of the fracture is investigated with online scanning electron microscope (SEM) observation and the parameters of non-essential work of fracture, β and w p , are calculated based on finite element (FE) method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Vlassak, J.J., Nix, W.D.: A new bulge testing technique for the determination of Young’s modulus and Possion’s ratio of thin films. J. Mater. Res. 7, 3242–3249 (1992)

    CAS  Google Scholar 

  2. Fang, W., Wickert, J.A.: Determining mean and gradient residual stress in thin films using micromachined cantilevers. J. Micromech. Microeng. 6, 301–309 (1996)

    Article  CAS  Google Scholar 

  3. Jansen, E., Obermeier, E.: Thermal conductivity measurements on thin films based on micromechanical devices. J. Micromech. Microeng. 6, 118–121 (1996)

    Article  CAS  Google Scholar 

  4. Ghosh, K.L., Mittal, K.L.: Polyimides, Fundamentals and Applications. Marcel Dekker, New York (1996)

    Google Scholar 

  5. Hsiue, G.H., Chen, J.K., Liu, Y.L.: Synthesis and characterization of nanocomposite of polyimide-silica hybrid film nanoaqueous sol–gel process. J. Appl. Phym. Sci. 76(11), 1609–1618 (2000)

    Article  CAS  Google Scholar 

  6. Tyan, H.L., Wei, K.H., Hsieh, T.E.: Mechanical properties of clay-polyimide (BTDA-ODA) nanocomposites via ODA-modified organnoclay. J. Polyl. Sci. Part B: Polym. Phys. 38, 2873–2878 (2000)

    Article  CAS  Google Scholar 

  7. Rice, J.R., Rosengran, G.R.: Plane strain deformation near a crack tip in a power-law hardening materials. J. Mech. Phys. Solids 16(1), 1–12 (1968)

    Article  Google Scholar 

  8. ASTM, ASTM E813-89: Standard Test Method for J1C, A measure of fracture toughness in 1989 Annual Book of ASTM Standards, ASTM, Philadelphia 700–709 (1989)

  9. Broberg, K.B.: On stable crack growth.. J. Mech. Phys. Solids 23, 215–237 (1975)

    Article  Google Scholar 

  10. Ferrer-Balas, D., Li, M. Maspoch, Martinez, A.B.: Fracture behaviour of polypropylene films at different temperatures: assessment of the EWF parameters. Polymer 42, 2665–2674 (2001)

    Article  CAS  Google Scholar 

  11. Hashemi, S.: Fracture of polybutylene temperature (PBT) film. Polym. Test. 43, 4033–4041 (2002)

    CAS  Google Scholar 

  12. Hashemi, S.: Effect of temperature on fracture toughness of an amorphous poly(ether–ether ketone) film using essential work of fracture analysis. Polym. Test. 22, 589–599 (2003)

    Article  CAS  Google Scholar 

  13. Cotterell, R., Reddel, J.K.: On the essential work of ductile fracture in polymers. Int. J. Fract. 13, 267 (1977)

    CAS  Google Scholar 

  14. Wu, J.S., Mai, Y.W.: The essential fracture work concept for toughness measurement of ductile polymers. Polym. Eng. Sci. 36(18), 2275–2288 (1996)

    Article  CAS  Google Scholar 

  15. Testing Protocol for Essential Work of Fracture, ESIS TC-4 Group, October (1997)

  16. Wang, Z.D., Lu, J.J., Li, Y., et al.: Low temperature properties of Pi/SiO2 nanocomposite films. Mat. Sci. Eng. B 123, 216–221 (2005)

    Article  Google Scholar 

  17. Ferrer-Balas, D., Li, M. Maspoch, Martinez, A.B.: Influence of annealing on the microstructural, tensile and fracture properties of polypropylene films. Polymer 42, 1697–1705 (2001)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was funded by Natural Science Foundation of China (No 10502005).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Z. D. Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, Z.D., Lu, J.J. Essential and Non-essential Work of Fracture of PI/SiO2 Hybrid Thin Films. Appl Compos Mater 14, 33–45 (2007). https://doi.org/10.1007/s10443-006-9029-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10443-006-9029-4

Key words

Navigation