Skip to main content
SpringerLink
Log in

Determination of Trace Sudan IV Residues in Foods Through Molecularly Imprinted SPE Coupled with LC

  • Original
  • Published:
Chromatographia Aims and scope Submit manuscript

Abstract

In this paper, a highly selective Sudan IV molecularly imprinted polymer was synthesized by surface molecular imprinting technique in combination with a sol–gel process using γ-aminopropyl triethoxysilane as functional monomer, tetraethoxysilane as cross-linker and activated silica gel as support material. The imprinted polymer was characterized by FT-IR spectra, scanning electron micrograph and adsorption experiments and it was exhibited good recognition and selective ability, offered a faster rate for the adsorption of Sudan IV. Using the imprinted material as sorbent, a solid-phase extraction coupled with high-performance liquid chromatography method for determination of trace Sudan IV was presented. The detection limit (S/N = 3) was 25.2 ng L−1, and the RSD for five replicate was 2.86%. With a loading flow rate of 2.5 mL min−1 for loading 30 mL, an enrichment factor of 104 was achieved. This method was applied for extraction and determination of chilli powder and duck egg samples with good recoveries ranging from 85.3 to 98.1%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Calbiani F, Careri M, Elviri L, Mangia A, Pistarà L, Zagnoni I (2004) J Chromatogr A 1042:123–130. doi:10.1016/j.chroma.2004.05.027

    Article  CAS  Google Scholar 

  2. Stiborova M, Martinek V, Rydlova H, Hodek P, Frei E (2002) Cancer Res 62:5678–5684

    CAS  Google Scholar 

  3. Nohynek GJ, Fautz R, Benech-Kieffer F, Toutain H (2004) Food Chem Toxicol 42:517–543. doi:10.1093/mutage/gep044

    Article  CAS  Google Scholar 

  4. Wang S, Xu ZX, Fang GZ, Duan ZJ, Zhang Y, Chen S (2007) J Agr Food Chem 55:3869–3876. doi:10.1021/jf070261t

    Article  CAS  Google Scholar 

  5. Puoci F, Garreffa C, Iemma F, Muzzalupo R, Spizzirri UG, Picci N (2005) Food Chem 93:349–353. doi:10.1016/j.foodchem.2004.11.014

    Article  CAS  Google Scholar 

  6. Du MJ, Han XG, Zhou ZH, Wu SG (2007) Food Chem 105:883–888. doi:10.1016/j.foodchem.2006.12.039

    Article  CAS  Google Scholar 

  7. Zhang ZH, Zhang HB, Hua YF, Yao SZ (2010) Anal Chim Acta 661:173–180. doi:10.1016/j.aca.2009.12.024

    Article  CAS  Google Scholar 

  8. Cornet V, Govaert Y, Moens G, Van Loco J, Degroodt JM (2006) J Agric Food Chem 54:639–644. doi:10.1021/jf0517391

    Article  CAS  Google Scholar 

  9. Ertaş E, Özer H, Alasalvar C (2007) Food Chem 105:756–760. doi:10.1016/j.foodchem.2007.01.010

    Article  Google Scholar 

  10. He LM, Su YJ, Fang BH, Shen XG, Zeng ZL, Liu YH (2007) Anal Chim Acta 594:139–146. doi:10.1016/j.aca.2007.05.021

    Article  CAS  Google Scholar 

  11. Mazzetti M, Fascioli R, Mazzoncini I, Spinelli G, Morelli I, Bertoli A (2004) Food Addit Contam 21:935–941. doi:10.1080/02652030400007252

    Article  CAS  Google Scholar 

  12. Zhang Y, Wu HL, Xia AL, Han QJ, Cui H, Yu RQ (2007) Talanta 72:926–931. doi:10.1016/j.talanta.2006.12.019

    Article  CAS  Google Scholar 

  13. Xu ZX, Wang S, Fang GZ, Song JJ, Zhang Y (2010) Chromatographia 71:397–430. doi:10.1111/j.1750-3841.2009.01416.x

    Article  CAS  Google Scholar 

  14. Tateo F, Bononi M (2004) J Agric Food Chem 52:655–658. doi:10.1021/jf030721s

    Article  CAS  Google Scholar 

  15. Mejia E, Ding YS, Mora MF, Garcia CD (2007) Food Chem 102:1027–1033. doi:10.1016/j.foodchem.2006.06.038

    Article  CAS  Google Scholar 

  16. Capitàn F, Capitàn-Vallvey LF, Fernandez MD, De Orbe I, Avidad R (1996) Anal Chim Acta 331:141–148. doi:10.1016/0003-2670(96)00192-4

    Article  Google Scholar 

  17. Gupta R, Kumar A (2008) Biotechnol Adv 26:533–547. doi:10.1016/j.biotechadv.2008.07.002

    Article  CAS  Google Scholar 

  18. Han DM, Fang GZ, Yan XP (2005) J Chromatogr A 1100:131–136. doi:10.1016/j.chroma.2005.09.035

    Article  CAS  Google Scholar 

  19. Olwill A, Hughes H, Riordain MO, Mcloughlin P (2004) Biosens Bioelectron 20:1045–1050. doi:10.1016/j.bios.2004.04.029

    Article  CAS  Google Scholar 

  20. Dickert FL, Hayden O (2002) Anal Chem 74:1302–1306. doi:10.1021/ac010642k

    Article  CAS  Google Scholar 

  21. Sreenivasan K (2006) Talanta 68:1037–1039. doi:10.1016/j.talanta.2005.05.005

    Article  CAS  Google Scholar 

  22. Fang GZ, Tan J, Yan XP (2005) Anal Chem 77:1734–1739. doi:10.1021/ac048570v

    Article  CAS  Google Scholar 

  23. (2005) The method for the determination of Sudan dyes in foods-high performance liquid chromatography, No. GB/T 19681-2005, China

  24. Ismail HM, Mansour SAA, Zaki MI (1992) Thermochim Acta 202:269–280. doi:10.1016/0040-6031(92)85171-Q

    Article  CAS  Google Scholar 

  25. Takei T, Eriguchi E, Fuji M, Watanabe T, Chikazawa M (1998) Thermochimica Acta 308:139–145. doi:10.1016/S0040-6031(97)00341-9

    Article  CAS  Google Scholar 

  26. Stafiej A, Pyrzynska K, Regan F (2007) J Sep Sci 30:985–991. doi:10.1002/jssc.200600433

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is grateful for financial supports from the Department of Science and Technology of Shandong Province, China (project No. 2009GG10009058), and the Youth Science and Technology funded project of Shandong Agricultural University, China.

Author information

Authors and Affiliations

  1. College of Food Science and Engineering, Shandong Agricultural University, Taian, 271018, China

    Xin Junhong, Zhao Dongyan, Zhang Limin, Xu Zhixiang & Qu Dejing

  2. College of Chemical and Material Science, Shandong Agricultural University, Taian, 271018, China

    Zhou Jie

Authors
  1. Xin Junhong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhao Dongyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zhang Limin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xu Zhixiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Zhou Jie
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Qu Dejing
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xu Zhixiang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Junhong, X., Dongyan, Z., Limin, Z. et al. Determination of Trace Sudan IV Residues in Foods Through Molecularly Imprinted SPE Coupled with LC. Chromatographia 73, 235–242 (2011). https://doi.org/10.1007/s10337-010-1889-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10337-010-1889-y

Keywords

Search

Navigation