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Determination of Phenylureas Herbicides in Foodstuffs Based on Matrix Solid-Phase Dispersion Extraction and RP-LC with UV Detection

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Abstract

A new method for simultaneous determination of seven kinds of phenylurea herbicides (PUHs) in solid foodstuffs was established based on matrix solid phase dispersion (MSPD)–RP-LC. The procedure of MSPD is simple and not time-consuming. C18-bonded silica and anhydrous alumina were, respectively, used as dispersion sorbent and purificant, and dichloromethane as extraction reagent. Under the optimum conditions, seven kinds of herbicides were separated completely within 30 min, response was a linear function of concentration over the range 2.5–500 μg L−1 with good correlation coefficients (>0.99) and lower detection limits (0.25 and 0.5 μg L−1). Intra-day and inter-day precision of the peak areas for seven PUHs were less than 3.7 and 5.3%. The new method was used to detect seven PUHs in four kinds of solid foodstuffs with average recoveries range from 73.1 to 101%.

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References

  1. Giacomazzi S, Cochet N (2004) Chemosphere 56:1021–1032

    Article  CAS  Google Scholar 

  2. Escuderos-Morenas ML, Santos-Delgado MJ, Rubio-Barroso S (2003) J Chromatogr A 1011:143–153

    Article  CAS  Google Scholar 

  3. Tadeo JL, Sdnchez-Brunete C (2003) Chromatographia 57:793–798

    Article  CAS  Google Scholar 

  4. Peña F, Cárdenas S, Gallego M, Valcárcel M (2002) Talanta 56:727–734

    Article  Google Scholar 

  5. Muñoz de la Peña A, Mahedero MC, Bautista-Sanchez A (2003) Talanta 60:279–285

    Article  Google Scholar 

  6. Mughari AR, Parrilla Vázquez P, Martínez Galera M (2007) Anal Chim Acta 593:157–163

    Article  CAS  Google Scholar 

  7. Mou RX, Chen MX, Zhi JL (2008) J Chromatogr B 875:437–443

    Article  CAS  Google Scholar 

  8. Li YT, George JE, McCarty CL, Wendelken SC (2006) J Chromatogr A 1134:170–176

    Article  CAS  Google Scholar 

  9. Bichon E, Dupuis M, Le Bizec B, André F (2006) J Chromatogr B 838:96–106

    Article  CAS  Google Scholar 

  10. Lin HH, Sung YH, Huang SD (2003) J Chromatogr A 1012:57–66

    Article  CAS  Google Scholar 

  11. Carabias-Martínez R, Rodríguez-Gonzalo E, Herrero-Hernández E, Hernández-Méndez J (2004) Anal Chim Acta 517:71–79

    Article  Google Scholar 

  12. Lawrence JF, Ménard C, Hennion M-C, Pichon V, Le Goffic F, Durand N (1996) J Chromatogr A 732:277–281

    Article  CAS  Google Scholar 

  13. Tamayo FG, Martin-Esteban A (2005) J Chromatogr A 1098:116–122

    Article  CAS  Google Scholar 

  14. Zhou QX, Ding YJ, Xiao JP (2006) Chromatographia 65:25–30

    Article  Google Scholar 

  15. Zhao E, Han L, Jiang S, Wang Q, Zhou Z (2006) J Chromatogr A 1114:269–274

    Article  CAS  Google Scholar 

  16. Khalili-Zanjani MR, Yamini Y, Yazdanfar N, Shariati S (2008) Anal Chim Acta 606:202–208

    Article  CAS  Google Scholar 

  17. Chou TY, Lin SL, Fu MR (2009) Talanta 80:493–498

    Article  CAS  Google Scholar 

  18. Barker SA, Long AR, Short CR (1989) J Chromatogr A 475:353–361

    Article  CAS  Google Scholar 

  19. Cheng JH, Liu M, Yu Y, Wang XP, Zhang HQ, Ding L, Jin HY (2009) Meat Sci 82:407–412

    Article  CAS  Google Scholar 

  20. García de Llasera MP, Reyes-Reyes ML (2009) Food Chem 114:1510–1516

    Article  Google Scholar 

  21. Zhu XL, Qi XY, Wang J, Yue JN, Sun ZD, Lei WJ (2007) Chromatographia 65:625–628

    CAS  Google Scholar 

  22. Qi XY (2010) Food Chem 121:758–762

    Article  CAS  Google Scholar 

  23. Walorczyk S (2008) Rapid Commun Mass Spectrom 22:3791–3801

    Article  CAS  Google Scholar 

  24. Abhilash PC, Jamil S, Singh N (2007) J Chromatogr A 1176:43–47

    Article  CAS  Google Scholar 

  25. de Rijke E, Out P, Niessen WMA, Ariese F, Gooijer C, UATh Brinkman (2006) J Chromatogr A 1112:31–63

    Article  Google Scholar 

  26. Kristenson EM, Brinkman Udo A Th, Ramos L (2006) Trends Anal Chem 25:96–111

  27. Bogialli S, Di Corcia A (2007) J Biochem Biophys Methods 70:163–179

    Article  CAS  Google Scholar 

  28. Xiao L, Wang YC, Cheng MR (2010) J Tea Sci 30(1):251–256

    Google Scholar 

Download references

Acknowledgments

This work was supported by the Testing Project Foundation of Zhejiang province science and technology department of China (2007F70051).

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Authors and Affiliations

  1. College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, 310036, People’s Republic of China

    Yuanchao Wang, Cheng Cai, Liang Xiao, Qiong Wu & Guojian Cheng

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  1. Yuanchao Wang
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  2. Cheng Cai
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  3. Liang Xiao
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  4. Qiong Wu
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  5. Guojian Cheng
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Correspondence to Yuanchao Wang.

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Wang, Y., Cai, C., Xiao, L. et al. Determination of Phenylureas Herbicides in Foodstuffs Based on Matrix Solid-Phase Dispersion Extraction and RP-LC with UV Detection. Chromatographia 73, 403–406 (2011). https://doi.org/10.1007/s10337-010-1870-9

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  • DOI: https://doi.org/10.1007/s10337-010-1870-9

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