Abstract
In this work, surface-relief-grating formation behavior was studied by using two hyperbranched azo polymers. The hyperbranched polymers containing pseudo-stilbene type azo chromophores throughout the hyperbranched structure were synthesized by step-growth polycondensation of AB2 type monomers. The AB2 monomer, 4-(4′-(bis(2-chloroethyl)amino)-phenylazo)benzoic acid (BAA), was prepared through azo-coupling reaction between N,N′-bis(2-chloroethyl)aniline and 4-aminobenzenic acid. The another AB2 monomer, 4-(4′-(bis(2-chloroethyl)amino)phenylazo)-3-nitro-benzoic acid (BANA), was prepared through azo-coupling reaction between N,N-bis(2-chloroethyl)aniline and 3-nitro-4-aminobenzenic acid. The hyperbranched polymers (PBAA and PBANA) were prepared through nucleophilic substitution reaction of BAA and BANA, respectively. The polymers synthesized were characterized by using spectroscopic methods and thermal analysis. The photoinduced dichroism and photo-induced surface-relief-grating (SRG) formation of the hyperbranched polymers were investigated upon irradiation with Ar+ laser at 488 nm. PBAA shows typical photoinduced dichroism SRG formation behavior. On the contrary, PBANA does not show the photoresponsive properties. The results indicate that the nitro at the ortho position of azo group of PBANA shows the effect of inhibiting the photoinduced variations. The effect can be attributed to the blockage of the trans-cis isomerization of the azobenzene moieties by the steric hindrance.
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Xie, S., Natansohn, A. and Rochon, P., Chem. Mater., 1993, 5: 403
Delaire, J.A. and Nakatani, K., Chem. Rev., 2000, 100: 1817
Natansohn, A. and Rochon, P., Chem. Rev., 2002, 102: 4139
Todorov, T., Nikolova, L. and Tomova, N., Appl. Opt., 1984, 23: 4309
Eich, M., Wendroff, J.H., Beck, B. and Ringsdorf, H., Makromol. Chem. Rapid Commun., 1987, 8: 59
Rochon, P., Batalla, E. and Natansohn, A., Appl. Phys. Lett., 1995, 66: 136
Kim, D., Tripathy, S., Li, L. and Kumar, J., Appl. Phys. Lett., 1995, 66: 1166
Barratt, C.J., Rochon, P. and Natansohn, A., J. Chem. Phys., 1998, 109: 1505
Pedersen, T.G., Johansen, P.M., Holme, N.C.R., Ramanujam, P.S. and Hilvsted, S., Phys. Rev. Lett., 1998, 80: 89
Lefin, P., Fiorini, C. and Nunzi, J.M., Pure Appl. Opt., 1998, 7: 71
Kumar, J., Li, L., Jiang, X.L., Kim, D.Y., Lee, T.S. and Tripathy, S.K., Appl. Phys. Lett., 1998, 72: 2096
Astruc, D., Boisselier, E. and Ornelas, C., Chem. Rev., 2010, 110: 1857
Li, W.S. and Aida, T., Chem. Rev., 2009, 109(11): 6047
Lee, C.C., MacKay, J.A., Frechet, J.M.J. and Szoka, F.C., Nat. Biotechnol., 2005, 23(12): 1517
Vogtle, F., Gestermann, S., Hesse, R., Schwierz, H. and Windisch, B., Prog. Polym. Sci., 2000, 25(7): 987
Vanhest, J.C.M, Delnoye, D.A.P, Baars, N.W.P.L., Vangenderen, M.H.P and Meijer, E.W., Science, 1995, 268: 1592
Mourey, T.H., Turner, S.R., Rubinstein, M., Frechet, J.M.J, Hawker, C.J. and Wooley, K.L., Macromolecules, 1992, 25(9): 2401
Percec, V. and Kawasumi, M., Macromolecules, 1992, 25(15): 3843
Voit, B., J. Polym. Sci. Part A: Polym. Chem., 2000, 38(14): 2505
Jikei, M. and Kakimoto, M., Prog. Polym. Sci., 2001, 26(8): 1233.
Yates, C.R. and Hayes, W., Eur. Polym. J., 2004, 40(7): 1257
Kim, Y. and Webster, O., Macromolecules, 1992, 25(21): 5561
Yan, D.Y., Zhou, Y.F. and Hou, J., Science, 2004, 303: 65
Chen, J.W., Peng, H., Law, C.C.W., Dong, Y.P., Lam, J.W.Y., Williams, I.D. and Tang, B.Z., Macromolecules, 2003, 36(12): 4319
Che, P.C., He, Y.N. and Wang, X.G., Macromolecules, 2005, 38: 8657
He, Y.N., Wang, X.G. and Zhou, Q.X., Synth. Met., 2003, 132: 245
Che, P.C., He, Y.N. and Wang, X.G., Acta Polymerica Sinica (in Chinese), 2006, (8): 970
Che, P.C., He, Y.N. and Wang, X.G., Acta Polymerica Sinica (in Chinese), 2007, (1): 21
He, Y.N., Li, Y.J., Yin, J.J. and Wang, X.G., Acta Polymerica Sinica (in Chinese), 2008, (2): 183
He, Y.N., Wang, X.G. and Zhou, Q.X., Polymer, 2002, 43: 7325
Fukuda, T., Matsuda, H., Shiraga, T., Kimura, T., Kato, M., Viswanathan, N., Kumar, J. and Tripathy, S.K., Macromolecules, 2000, 33: 4220
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Che, Pc., He, Yn. & Wang, Xg. Surface-relief-grating formation behavior of two hyperbranched azo polymers. Chin J Polym Sci 30, 478–486 (2012). https://doi.org/10.1007/s10118-012-1142-2
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DOI: https://doi.org/10.1007/s10118-012-1142-2