Abstract
Cross-linked poly(diallyldimethylammonium chloride) and its derivative copolymers were synthesized and used as phase transfer catalyst in the nucleophilic substitution reaction especially halogen exchange reactions. In addition, the effect of hydrophilic-hydrophobic character of the polymers in the nucleophilic reactions was investigated.
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Naik, D.S. and Doraiiswamy, L.K., AIChE J., 1998, 44: 612
Mahdavi, H., Haghani, E. and Malakian, B., React. Funct. Polym., 2006, 66: 1033
Luo, J., Lü, C.X., Cai, C. and Qü, W.C., J. Fluorine Chem., 2004, 125: 701
Chen, Z.X., Xu, G.Y., Yang, G.C. and Wang, W., React. Funct. Polym., 2004, 61: 139
Akelah, A. and Moet, A., “Functionalized polymers and their applications”, Chapman and Hall, New York, 1990, p. 110
Butler, G.B. and Ingley, F.L., J. Am. Chem. Soc., 1951, 72: 894
Wandrey, C., Jaeger, W. and Reinisch, W.G., Acta Polym., 1981, 32: 197
Jaeger, W., Hahn, M. and Wandrey, C., in “Polymer reaction engineering”, eds. by Reichert, K.H. and Geiseler, W., VCH Weinheim, Lausanne, 1989, p. 239
Butler, G.B., “Cyclopolymerization and cyclocopolymerization”, Marcel Dekker, New York, 1992, p. 10
Butler, G.B. and Zhang, N.Z., “Water soluble polymers” (ACS Symposium Series 467), eds. by Shalaby, W., Mc Cormic, C.L. and Butler, G.B., American Chemical Society, Washington DC, 1991, p. 25
Jaeger, W., Gohlke, U., Hahn, M., Wandrey, C. and Dietrich, K., Acta Polym., 1989, 40: 161
Dautzenberg, H., Jaeger, W., Kötz, B., Philipp, J., Seidel, C. and Stscherbina, D., “Polyelectrolytes: formation, characterization, application”, Carl Hanser Verlag, München, 1994
Wandrey, C., Hernandez, J., Barjas, B. and Hunkeler, D., Adv. Polym. Sci., 1999, 45: 123
Mahdavi, H. and Haghani, E., Chinese J. Chem., 2008, 26: 1
Tuzun, N.S., Aviyente, V. and Houk, K.N., J. Org. Chem., 2002, 67: 5068
Wang, G.J. and Engberts, J.B.F.N., J. Org. Chem., 1994, 59: 4076
Ali, M.M., Perzanowski, H.P. and Ali, S.A., Polymer, 2002, 41: 5591
Butler, G.B. and Angelo, R.J., J. Am. Chem. Soc., 1957, 79: 3128
Butler, G.B. and Ingley, F.L., J. Am. Chem. Soc., 1951, 72: 894
Boothe, J., Flock, E. and Hoover, M.F., J. Macromol Chem. A, 1970, 4: 1419
Butler, G.B., Do, C.H., in “Water soluble polymers” (ACS Sumposium Series 467), eds. by Shalaby, W., Mc Cormic, C.L. and Butler, G.B., American Chemical Society, Washington DC, 1991, p. 151
Gordon, J.E. and Kutina, R.E., J. Am. Chem. Soc., 1977, 99: 3903
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Hossein, M., Mahdi, M. Synthesis and applications of cross-linked poly(diallyldimethyl ammonium chloride) and its derivative copolymers as efficient phase transfer catalyst for nucleophilic substitution reactions. Chin J Polym Sci 29, 165–172 (2011). https://doi.org/10.1007/s10118-010-1027-1
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DOI: https://doi.org/10.1007/s10118-010-1027-1