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Fabrication and characterization of poly 2-napthol orange film modified electrode and its application to selective detection of dopamine

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Abstract

The present work is based on the use of a redox mediator containing an azo group for the selective determination of dopamine in the presence of uric acid and ascorbic acid by electrochemical method. A modified electrode was prepared by electrochemical polymerization of the poly 2-napthol orange film (P2NO) on the paraffin wax-impregnated graphite electrode (PIGE) by applying potential between −0.6 and 0.8 V at scan rate of 50 mV s−1 for 30 segments. The modified P2NO film electrode was characterized by ATR-IR spectroscopy, FE-SEM, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), differential pulse voltammetry (DPV), hydrodynamic voltammetry (HDV), and chronoamperometry (CA). The P2NO film modified electrode exhibited selective determination of dopamine in the presence of uric acid and ascorbic acid, and the electrocatalytic activity for oxidation of dopamine was excellent. The linear range for the determination of dopamine was 0.6 to 250 μM with a limit of detection of 0.13 μM. The modified P2NO electrode showed good stability and reproducibility. The modified electrode was used for real sample analysis such as human blood serum, rat blood serum, and pharmaceutical samples (dopamine hydrochloride injection). The results obtained were found to be satisfactory.

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Acknowledgements

The authors acknowledge the financial assistance from University Grants Commission (UGC)–New Delhi, India, and the National Center for Nanoscience and Nanotechnology for Recording FE-SEM Techniques and National Center for Ultrafast Process for Recording ATR-IR Spectra, University of Madras.

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  1. Department of Analytical Chemistry, School of Chemical Sciences, University of Madras, Guindy Campus, Chennai, 600 025, India

    Ramalingam Manikandan, P.N. Deepa & Sangilimuthu Sriman Narayanan

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  1. Ramalingam Manikandan
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Correspondence to Sangilimuthu Sriman Narayanan.

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Manikandan, R., Deepa, P. & Narayanan, S.S. Fabrication and characterization of poly 2-napthol orange film modified electrode and its application to selective detection of dopamine. J Solid State Electrochem 21, 3567–3578 (2017). https://doi.org/10.1007/s10008-017-3604-5

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