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Effect of mixed valence state of titanium on reduced recombination for natural dye-sensitized solar cell applications

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Abstract

Nanocrystalline TiO2 was prepared using water-assisted hydrothermal technique. X-ray diffraction pattern confirms the formation of tetragonal anatase phase, and it was further confirmed with Raman results. Williamson-Hall (W-H) plot reveals an induced strain in the sample and the calculated crystallite size of 15 nm is in accordance with the XRD results. Strain induced in the sample is due to creation of oxygen vacancies (defect), and it is responsible for the mixed valence state of Ti atom (Ti3+ and Ti4+) which is confirmed by X-ray photoelectron spectroscopy. Impedance studies result in increased conductivity of oxygen defect-based TiO2 due to its fast electron hopping between the mixed valence states. High-resolution scanning electron microscopic (HR-SEM) image shows a well-agglomerated spherical-shaped nanoparticle with high surface area of 152 m2/g. Here, we report for the first time the effect of mono and co-sensitization of natural dyes on the prepared TiO2 photoanode for dye-sensitized solar cell (DSSC) applications. The interfacial charge transfer resistance, chemical capacitance and electron recombination lifetime of the devices were examined using electrochemical impedance spectroscopy (EIS) analysis, and the performance of the best photoanode was studied using standard solar simulator at 1 Sun intensity (AM 1.5 G).

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Acknowledgements

This work was supported through research grant from University Grants Commission (UGC), India [41-915/2012 (SR) dt, 26 July 2012]. The authors thank UGC for the financial grant; National Center for Nanoscience and Nanotechnology (NCNSNT), University of Madras, Chennai, India for the XPS studies; Indian Institute of Technology, Madras for the HRSEM (Chemical Engineering Lab) and BET analyses (Department of Chemistry); and Center for Nano Science and Engineering (CeNSE), Indian Institute of Science, Bangalore, India for the photovoltaic (J-V) measurements.

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  1. Department of Nuclear Physics, University of Madras, Guindy Campus, Chennai, 600 025, Tamil Nadu, India

    K. Ashok Kumar, K. Subalakshmi & J. Senthilselvan

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Kumar, K.A., Subalakshmi, K. & Senthilselvan, J. Effect of mixed valence state of titanium on reduced recombination for natural dye-sensitized solar cell applications. J Solid State Electrochem 20, 1921–1932 (2016). https://doi.org/10.1007/s10008-016-3191-x

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