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Partially graphitized ordered mesoporous carbons for high-rate supercapacitors

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Abstract

Partially graphitized ordered mesoporous carbons have been prepared with a soft template method using low-molecular-weight phenolic resol as a carbon source, triblock copolymer F127 as a template, and ferric citrate as a graphitization catalyst. N2 sorption and transmission electron microscopy analysis show that the ordered mesoporous carbons have been partially graphitized when the carbonization temperature is above 700 °C. The graphitic ordered mesoporous carbons exhibit better rate performance than amorphous ordered mesoporous carbons. The specific capacitance of the graphitic ordered mesoporous carbons (GOMCs) prepared at 700 °C reaches to 112 F g−1 at a scan rate of up to 1,000 mV s−1. Its capacitance retention ratio is 64 %, which is much higher than that of the amorphous ordered mesoporous carbons prepared at 600 °C (33 %). High electronic conductivity and ordered mesoporous structure lead to the high electrochemical performance of the partially graphitized ordered mesoporous carbons.

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Acknowledgments

This work was supported by the National Science Foundation of China (51177156/E0712) and the Project to Support Xinjiang with Science and Technology from Chinese Academy of Sciences (XBXJ-2011-041).

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Authors and Affiliations

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, China

    Liang Jiang, Jingwang Yan, Rong Xue, Gongquan Sun & Baolian Yi

  2. Dalian National Laboratory for Clean Energy, 457 Zhongshan Road, Dalian, 116023, China

    Liang Jiang, Jingwang Yan, Rong Xue, Gongquan Sun & Baolian Yi

  3. University of Chinese Academy of Sciences, Beijing, 100049, China

    Liang Jiang

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  1. Liang Jiang
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  2. Jingwang Yan
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  3. Rong Xue
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  5. Baolian Yi
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Correspondence to Jingwang Yan.

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Jiang, L., Yan, J., Xue, R. et al. Partially graphitized ordered mesoporous carbons for high-rate supercapacitors. J Solid State Electrochem 18, 2175–2182 (2014). https://doi.org/10.1007/s10008-014-2458-3

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  • DOI: https://doi.org/10.1007/s10008-014-2458-3

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