Abstract
The electrochemical reduction of carbon dioxide (CO2) is investigated in acetonitrile with tetrabutylammonium perchlorate as an electrolyte using a lead cathode and a sacrificial zinc anode, and the product under such a setup is insoluble zinc oxalate at potentials between −2.2 and −2.8 V vs. Ag rod electrode. Preelectrolysis is an effective method to remove the water in the electrolyte, which makes a distinct reduction peak of CO2 appear at −2.6 V vs. Ag on cyclic voltammogram. Even trace amounts of water in the electrolyte can interfere with the faradaic efficiency of reduction of CO2 to oxalate, and the product could be β-ZnC2O4 (in anhydrous solution) or ZnC2O4 · 2H2O (if water exists). The faradaic efficiency for oxalate production also depends on the cathode potential and the temperature, and the maximum is 96.8 % at −2.6 V vs. Ag and 5 °C. This is the highest value of CO2 electrochemical reduction found in the literature under ambient pressure.
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Acknowledgments
This work was supported by the Department of Education for the Fundamental Research Funds for the Central Universities, Jiangsu Province, for the college graduate research and innovation projects (CXLX13_086 and CXLX12_0105).
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Lv, W., Zhang, R., Gao, P. et al. Electrochemical reduction of carbon dioxide with lead cathode and zinc anode in dry acetonitrile solution. J Solid State Electrochem 17, 2789–2794 (2013). https://doi.org/10.1007/s10008-013-2186-0
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DOI: https://doi.org/10.1007/s10008-013-2186-0