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Partial stripping of Ag atoms from silver bilayer on a Au(111) surface accompanied with the reductive desorption of hexanethiol SAM

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Abstract

The interfacial structures of Ag bilayer prepared by underpotential deposition on Au(111) (Ag(2ML)/Au(111)) were determined by ex situ scanning tunneling microscopy and in situ surface X-ray scattering measurements before and after oxidative adsorption and after reductive desorption of a self-assembled monolayer (SAM) of hexanethiol (C6SH) in alkaline ethanol solution. While no structural change was observed after oxidative formation of C6SH SAM on the Ag(2ML)/Au(111) in an ethanol solution containing 20 mM KOH and 0.1 mM C6SH, some of the Ag atoms in the bilayer were stripped when the SAM was reductively desorbed.

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Acknowledgments

This work was partially supported by Grants-in-Aids for Scientific Research (KAKENHI; No. 18205016) from the Ministry of Education, Culture, Sports, Science, and Technology. The synchrotron radiation experiments were performed as projects by the Japan Synchrotron Radiation Research Institute (JAERI; proposal No. 2005B0174).

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Authors and Affiliations

  1. Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1, Ohtsuka, Bunkyo-ku, Tokyo, 112-8610, Japan

    Toshihiro Kondo

  2. Japan Atomic Energy Agency, Koto, Sayo-cho, Hyogo, 679-5148, Japan

    Kazuhisa Tamura, Masamitu Takahasi & Jun’ichiro Mizuki

  3. Physical Chemistry Laboratory, Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, 060-0810, Japan

    Satoru Takakusagi, Ken Kitamura & Kohei Uosaki

Authors
  1. Toshihiro Kondo
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  2. Kazuhisa Tamura
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  3. Satoru Takakusagi
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  4. Ken Kitamura
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  5. Masamitu Takahasi
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  6. Jun’ichiro Mizuki
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  7. Kohei Uosaki
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Corresponding author

Correspondence to Kohei Uosaki.

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Dedicated to Professor J. O’M. Bockris on the occasion of his 85th birthday.

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Kondo, T., Tamura, K., Takakusagi, S. et al. Partial stripping of Ag atoms from silver bilayer on a Au(111) surface accompanied with the reductive desorption of hexanethiol SAM. J Solid State Electrochem 13, 1141–1145 (2009). https://doi.org/10.1007/s10008-008-0764-3

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  • DOI: https://doi.org/10.1007/s10008-008-0764-3

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