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Electrosorption of carbon dioxide on platinum group metals and alloys—a review

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Abstract

The review summarizes the studies on the phenomenon of carbon dioxide electrosorption on platinum group metals and alloys. This subject is strictly linked to the research in the field of electrocatalysis and fuel cells. The work aims to present current knowledge on the processes of CO2 electrosorption and the adsorbate oxidation on Pt, Rh, and their alloys as well as on the influence of various factors on the electrochemical behavior of reduced CO2 on these materials. The experimental methods commonly applied in these investigations are characterized from the point of view of their ability to determine the nature of the adsorbate. The problem of similarities and differences between reduced CO2 and adsorbed CO is also discussed.

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Acknowledgements

The research was financed within a framework of 6FP HydroNanoPol project and a SPB HydroNanoPol project financially supported by the Ministry of Science and Higher Education (MNiSW).

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  1. Department of Chemistry, Warsaw University, Pasteura 1, 02-093, Warsaw, Poland

    M. Łukaszewski & A. Czerwiński

  2. Industrial Chemistry Research Institute, Rydygiera 8, 01-793, Warsaw, Poland

    H. Siwek & A. Czerwiński

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Łukaszewski, M., Siwek, H. & Czerwiński, A. Electrosorption of carbon dioxide on platinum group metals and alloys—a review. J Solid State Electrochem 13, 813–827 (2009). https://doi.org/10.1007/s10008-008-0618-z

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