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MCM-41-SO3H: a novel reusable nanocatalyst for synthesis of amidoalkyl naphthols under solvent-free conditions

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Abstract

Nanosized MCM-41-SO3H based on an ordered mesoporous material with covalently anchored sulfuric acid groups inside the mesochannels was used as an acid catalyst for synthesis of amidoalkyl naphthols in the multicomponent reaction of 2-naphthol, aromatic aldehydes, and an amide. The products were characterized by Fourier-transform infrared (FT–IR), nuclear magnetic resonance (NMR), and mass spectroscopy. The surface area and pore size of MCM-41-SO3H were also determined by the Brunauer–Emmett–Teller (BET) calculation model. This novel approach for preparation of amidoalkyl naphthols offers several advantages: short reaction times, simple purification and simple isolation of products, high reusability of the catalyst, to name but a few.

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Acknowledgments

We are grateful to the K. N. Toosi University of Technology Research Council for partial financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, K.N.Toosi University of Technology, Tehran, Iran

    Shahnaz Rostamizadeh, Fatemeh Abdollahi & Ali Mohammad Amani

  2. Biochemistry Lab, Pasteur Institute of Iran, P.O. Box 13164, Tehran, Iran

    Nasrin Shadjou

Authors
  1. Shahnaz Rostamizadeh
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  2. Fatemeh Abdollahi
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  3. Nasrin Shadjou
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  4. Ali Mohammad Amani
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Correspondence to Shahnaz Rostamizadeh.

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Rostamizadeh, S., Abdollahi, F., Shadjou, N. et al. MCM-41-SO3H: a novel reusable nanocatalyst for synthesis of amidoalkyl naphthols under solvent-free conditions. Monatsh Chem 144, 1191–1196 (2013). https://doi.org/10.1007/s00706-013-0936-4

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  • DOI: https://doi.org/10.1007/s00706-013-0936-4

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