Abstract
Low field inverse magnetocaloric effect (IMCE) associated with first-order martensitic transition in Ni50−x Mn37+x In13 (x=3,4,5) alloys was investigated. By tuning the composition of Ni/Mn, large change in the magnetization occurring between martensite and austenite phases in a narrow temperature interval was achieved, which results in large IMCE. Under low magnetic field change of 2 T, a large positive magnetic entropy change (ΔS M ) of 23.5 J/kg K with a net refrigeration capacity of 53 J/kg was obtained near room temperature (308 K) in the x=3 alloy. The results show that a small variation in Ni/Mn ratio significantly influences the martensitic transition temperature and the associated magnetic and magnetocaloric properties.
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References
V.K. Pecharsky, K.A. Gschneidner Jr., Phys. Rev. Lett. 78, 4494 (1997)
O. Tegus, E. Brück, K.H.J. Buschow, F.R. de Boer, Nature (Lond.) 415, 150 (2002)
F.X. Hu, B.G. Shen, J.R. Sun, Z.H. Cheng, G.H. Rao, X.X. Zhang, Appl. Phys. Lett. 78, 3675 (2001)
F.X. Hu, B.G. Shen, J.R. Sun, Appl. Phys. Lett. 76, 3460 (2000)
T. Krenke, E. Duman, M. Acet, E.F. Wassermann, X. Moya, L. Mañosa, A. Planes, Nat. Mater. 4, 450 (2005)
K. Oikawa, W. Ito, Y. Imano, Y. Sutou, R. Kainuma, K. Ishida, S. Okamoto, O. Kitakami, T. Kanomata, Appl. Phys. Lett. 88, 122507 (2006)
M. Khan, N. Ali, S. Stadler, J. Appl. Phys. 101, 053919 (2007)
A.K. Pathak, M. Khan, I. Dubenko, S. Stadler, N. Ali, Appl. Phys. Lett. 90, 262504 (2007)
A.K. Pathak, I. Dubenko, S. Stadler, N. Ali, J. Phys. D: Appl. Phys. 41, 202004 (2008)
Z.D. Han, D.H. Wang, C.L. Zhang, S.L. Tang, B.X. Gu, Y.W. Du, Appl. Phys. Lett. 89, 182507 (2006)
T. Krenke, M. Acet, E.F. Wassermann, X. Moya, L. Mañosa, A. Planes, Phys. Rev. B 73, 174413 (2006)
V.A. Chernenko, J. Pons, E. Cesari, K. Ishikawa, Acta Mater. 53, 5071 (2005)
X. Zhou, W. Li, H.P. Kunkel, G. Williams, J. Magn. Magn. Mater. 293, 854 (2005)
Z.D. Han, D.H. Wang, C.L. Zhang, H.C. Xuan, B.X. Gu, Y.W. Du, Appl. Phys. Lett. 90, 42507 (2007)
K.A. Gschneidner Jr., V.K. Pecharsky, A.O. Tsokol, Rep. Prog. Phys. 68, 1479 (2005)
S. Stadler, M. Khan, J. Mitchell, N. Ali, A.M. Gomes, I. Dubenko, A.Y. Takeuchi, A.P. Guimarães, Appl. Phys. Lett. 88, 192511 (2006)
B. Hernando, J.L. Sánchez Llamazares, J.D. Santos, V.M. Prida, D. Baldomir, D. Serantes, R. Varga, J. González, Appl. Phys. Lett. 92, 132507 (2008)
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Rama Rao, N.V., Gopalan, R., Chandrasekaran, V. et al. Large low-field inverse magnetocaloric effect near room temperature in Ni50−x Mn37+x In13 Heusler alloys. Appl. Phys. A 99, 265–270 (2010). https://doi.org/10.1007/s00339-009-5517-3
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DOI: https://doi.org/10.1007/s00339-009-5517-3