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A route to polysiloxanes with pendant imidazole groups

Hydrosilylation of N-allylimidazole hydrochloride with methyldichlorosilane

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Summary

Hydrosilylation of N-allylimidazole hydrochloride by methyldichlorosilane (MeCl2SiH) under mild conditions leads to a high yield of N-[γ-(methyldichlorosilyl)propyl]imidazole hydrochloride — highly reactive monomer for synthesis of imidazole modified polysiloxanes. This compound was used as the substrate for the generation of new cyclooligosiloxanes with the imidazole group attached through the trimethylene bridge to a siloxane ring. The anionic ring-opening polymerization of these cyclics permits the controlled synthesis of polysiloxanes with imidazole groups pendant to the polymer chain.

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Authors and Affiliations

  1. Centre of Molecular and Macromolecular Studies of the Polish Academy of Sciences, ul. Sienkiewicza 112, PL-90-363, Lódź, Poland

    Witold Fortuniak & Julian Chojnowski

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  1. Witold Fortuniak
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  2. Julian Chojnowski
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Fortuniak, W., Chojnowski, J. A route to polysiloxanes with pendant imidazole groups. Polymer Bulletin 38, 371–378 (1997). https://doi.org/10.1007/s002890050062

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  • DOI: https://doi.org/10.1007/s002890050062

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