Skip to main content
Log in

Occurrence of furosine and hydroxymethylfurfural as markers of thermal damage in dehydrated vegetables

  • Original Paper
  • Published:
European Food Research and Technology Aims and scope Submit manuscript

Abstract

The presence of furosine and hydroxymethylfurfural (HMF) as markers of thermal damage in commercial dehydrated vegetables has been studied. Furosine was measured in all the analysed samples whereas HMF was detected only in garlic, onion, and tomato groups and some other individual vegetables. Furosine, as indicator of the first steps of the Maillard reaction, ranged from 1.12 to 923 mg/100 g protein (depending on the vegetable species and thermal treatment applied) and was well correlated with the browning development in not severely heat-treated samples. In addition, the results seem to indicate that reducing sugars play an important role in the formation of furosine in some vegetable species but not HMF at the conditions used for the dehydration process. The findings of this study show the usefulness of furosine as a quality indicator for sensitive control of the dehydration process in vegetables.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1

Similar content being viewed by others

References

  1. Davoodia MG, Vijayanandb P, Kulkarnib SG, Ramana KV (2007) Lebbesm Wissens Technol 40:1832–1840

    Google Scholar 

  2. Hunter KJ, Fletcher JM (2002) Innovat Food Sci Emerg Technol 3:399–406

    Article  CAS  Google Scholar 

  3. Mirkìc M, Emiliano C, Dalla Rosa M, Sacchetti G (2006) J Sci Food Agric 86:1559–1566

    Article  Google Scholar 

  4. Legault RR, Hendel CE, Talburt WF (1954) Food Technol 8:143–149

    CAS  Google Scholar 

  5. Peleg Y, Mannheim CH, Berk Z (1970) J Food Sci 35:513–517

    Article  Google Scholar 

  6. Krow LW (1994) Food Chem 45:1570–1573

    Google Scholar 

  7. Berg HE, Van Boekel MAJS (1994) Neth Milk Dairy J 48:157–175

    CAS  Google Scholar 

  8. Ibarz A, Pagán J, Garza S (2000) J Sci Food Agric 80:1162–1168

    Article  CAS  Google Scholar 

  9. Rada-Mendoza M, Sanz M, Olano A, Villamiel M (2004) Food Chem 85:605–609

    Article  CAS  Google Scholar 

  10. Fernández-Artigas P, Guerra-Hernández E, García-Villanova B (1999) J Agric Food Chem 47:2872–2878

    Article  Google Scholar 

  11. Murkovic M, Pichler N (2006) Mol Nutr Food Res 50:842–846

    Article  CAS  Google Scholar 

  12. Esteve MJ, Frígola A, Rodrigo C, Rodrigo D (2002) Food Chem Toxicol 43:1413–1422

    Google Scholar 

  13. Gomis DB, Gutierrez MD, Sopeña L, Mangas JJ (1991) Chromatographia 32:45–48

    Article  Google Scholar 

  14. Teixidó E, Santos FJ, Puignou L, Galceran MT (2006) J Chromatogr A 1135:85–90

    Article  Google Scholar 

  15. Hidalgo A, Pompei C, Zambuto R (1998) J Agric Food Chem 46:4387–4390

    Article  CAS  Google Scholar 

  16. Cardelle-Cobas A, Moreno FJ, Corzo N, Olano A, Villamiel M (2005) J Agric Food Chem 53:9078–9082

    Article  CAS  Google Scholar 

  17. Sanz ML, del Castillo MD, Corzo N, Olano A (2001) J Agric Food Chem 49:5228–5231

    Article  CAS  Google Scholar 

  18. Schräder I, Eichner K (1996) Z Lebensm Unters Forsch 202:474–480

    Article  Google Scholar 

  19. Molnár-Perl I, Pinter-Szakács M, Wittmann R, Reutter M, Eichner K (1986) J Chromatogr 361:311–320

    Article  Google Scholar 

  20. Resmini P, Pellegrino L (1991) Int Chromatogr Lab 6:7–11

    Google Scholar 

  21. Guerra-Hernández E, Corzo N, García-Villanova B (1999) J Cereal Sci 29:171–176

    Article  Google Scholar 

  22. Olano Martínez-Castro I (1996) Nonenzymatic browning. In: Nollet L (ed) Handbook of food analysis, vol 2. Dekker, New York, pp 1683–1721

    Google Scholar 

  23. García-Villanova B, Guerra-Hernández E, Martínez-Gómez E, Montilla J (1993) J Agric Food Chem 41:1254–1255

    Article  Google Scholar 

  24. Rufián-Henares JA, Delgado-Andrade C, Morales FJ (2006) J AOAC Int 89:161–165

    Google Scholar 

  25. ADOGA (1976) Official standards and methods of the American dehydrated onion and garlic association for dehydrated onion and garlic products. ADOGA, San Francisco

    Google Scholar 

  26. Schoorl N (1971) Analysis of reducing sugars in Snell-Etter, encyclopedia of industrial chemical analysis, vol 11. Wiley, New York, pp 41–42

    Google Scholar 

  27. AOAC (1990) Method 920.165. Official methods of analysis of the association of official analytical chemist. In: Helrich K (ed), 15th edn, vol 2. Association of Official Analytical Chemists, Arlington, p 1000

  28. USDA (2005) National nutrient database for standard reference. http://www.nal.usda.gov/fnic/foodcomp/search/

  29. Labuza TP, Saltmarch M (1991) The non-enzymatic browning reaction as affected by water in foods. In: Rockland LB, Stewart GF (eds) Influences on food quality. Academic Press, New York, pp 605–650

    Google Scholar 

  30. Adam E, Mühlbauer W, Esper A, Wolf W, Spiess W (2000) Nahrung 44:32–37

    Article  CAS  Google Scholar 

  31. Lewicki PP, Pomaranska-Lazuka W, Witrowa-Rajchert D, Nowak D (1998) Pol J Food Nutr Sci 48:701–706

    Google Scholar 

  32. Kim H, Jo KS, Kwon DY, Park MH (1992) J Korean Agric Chem Soc 35:6–9

    CAS  Google Scholar 

  33. Rapusas RS, Driscoll RH (1995) J Food Eng 24:417–429

    Article  Google Scholar 

  34. Saltmarch M, Vagnini-Ferrari M, Labuza TP (1981) Prog Food Nutr Sci 5:331–344

    Google Scholar 

  35. Rufián-Henares JA, García-Villanova B, Guerra-Hernández E (2001) J Liq Chromatogr Relat Technol 24:3049–3061

    Article  Google Scholar 

  36. Hidalgo A, Pompei C (2000) J Agric Food Chem 48:78–82

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This research was supported by a “Ramón y Cajal” contract obtained from the Spanish Ministry of Education and Science and by a research project from Comisión Interministerial de Ciencia y Tecnología (AGL-2006-12656/ALI). We are grateful to Verbionat-Verbiotech for providing the studied samples.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to José A. Rufián-Henares.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rufián-Henares, J.A., García-Villanova, B. & Guerra-Hernández, E. Occurrence of furosine and hydroxymethylfurfural as markers of thermal damage in dehydrated vegetables. Eur Food Res Technol 228, 249–256 (2008). https://doi.org/10.1007/s00217-008-0929-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00217-008-0929-4

Keywords

Navigation