Skip to main content
Log in

Persistence Behaviour of Fungicide Mixture (Benalaxyl-M 4% + Mancozeb 65%) WP in Grapes

  • Published:
Bulletin of Environmental Contamination and Toxicology Aims and scope Submit manuscript

Abstract

Benalaxyl-M [methyl N-phenylacetyl-N-2, 6-xylyl-dl-alaninate] is a newly introduced phenyl-amide fungicide whereas Mancozeb is one of the member of ethylenebisdiothiocarbamate (EBDC) fungicide. Benalaxyl-M in combination with Mancozeb effectively controls downy mildew of grapes. A two season field trial was conducted under West Bengal climatic condition during 2009–2010 to evaluate the dissipation pattern of fungicide mixture (Benalaxyl-M 4 % + Mancozeb 65 %) WP in grapes at two application rates (2,750 g and 5,500 g ha−1). The quantitative analysis was performed using liquid chromatography–mass spectrometry (LC–MS/MS) and UV–Vis spectrophotometer for Benalaxyl-M and Mancozeb residues respectively. Following the first order kinetics the fungicide Benalaxyl-M dissipates in grapes with half-life (T1/2) value ranges between 2.59 and 2.79 days irrespective of seasons and doses. The dissipation pattern of Mancozeb also follows first order kinetics with half-life (T1/2) value ranges between 3.86 and 4.93 days irrespective of seasons and doses.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  • Banerjee K, Oulkar DP, Adsule PG (2008) Persistence and residue dynamics ofMancozeb and its toxic metabolite ethylene thiourea (ETU) in table grapes. Acta Hort 785:409–412

    Google Scholar 

  • Cabras P, Angioni A (2000) Pesticide residues in grapes, wine, and their processing products. J Agric Food Chem. 48(4):967–973

    Article  CAS  Google Scholar 

  • Dethe MD, Rane SD, Kale VD (1993) Residues of fungicides used against downy mildew of grapes. J Maharashtra Agric Univ 18(1):150–151

    CAS  Google Scholar 

  • Egger E (2001) Trends and new products for the protection of grapevines. Infor Agrar 57(15):75–86

    Google Scholar 

  • FAOSTAT (2007) FAO Statistical Database. http://www.fao.org. Accessed on 4 May 2009

  • Gonzalez Rodriguez RM, Cancho Grande B, Simal Gandara J (2009) Efficacy of new commercial formulations to control downy mildew and dissipation of their active fungicides in wine after good agricultural practices. J Sci Food Agric 89(15):2625–2635

    Article  CAS  Google Scholar 

  • Gozzo F, Pizzingrilli G, Valcamonica C (1988) Chemical evidence of the effects of mancozeb on benalaxyl in grape plants as possible rationale for their synergistic interaction. Pesticide Biochem Physio 30(2):136–141

    Article  CAS  Google Scholar 

  • Monchiero M, Gullino ML, Garibaldi A (1996) Results of control trials against Plasmopara viticola in Piedmont. Infor Fitopatologico 46(11):46–48

    Google Scholar 

  • Navarro S, Oliva J, Navarro G, Barba A (2001) Dissipation of chlorpyrifos, fenarimol, mancozeb, metalaxyl, penconazole, and vinclozolin in grapes. Am J Enol Vitic 52(1):35–40

    CAS  Google Scholar 

  • Pezzuto JM (2008) Grapes and human health: a perspective. J Agric Food Chem 56:6777–6784

    Article  CAS  Google Scholar 

  • Tomlin CDS (1997) The pesticide manual. British Crop Product Council, Surrey

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Anjan Bhattacharyya.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kundu, C., Goon, A. & Bhattacharyya, A. Persistence Behaviour of Fungicide Mixture (Benalaxyl-M 4% + Mancozeb 65%) WP in Grapes. Bull Environ Contam Toxicol 89, 1253–1257 (2012). https://doi.org/10.1007/s00128-012-0847-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00128-012-0847-9

Keywords

Navigation