Abstract
2-acetamidopyridine-1-oxide (AcAmPyO) complexes of six lanthanide perchlorates, with the general composition Ln(AcAmPyO)5 (ClO4)3, have been synthesized and characterized by analysis, molar conductance, infrared, proton NMR and electronic spectral data. Infrared and conductance studies indicate the ionic nature of the anion. The coordination of the ligand through the N-O and C=O moieties is shown by the infrared and proton NMR spectral analysis.
Similar content being viewed by others
References
Behrendt J R and Madan S K 1976J. Inorg. Nucl. Chem. 38 1827
Geary W J 1971Coord. Chem. Rev. 7 81
Navaneetham N S and Soundararajan S 1979Inorg. Nucl. Chem. Lett. 15 379
Ochidi E 1967Aromatic Amine Oxides (Amsterdam: Elsevier) p. 24
Rajasekar N 1980Studies in lanthanide chemistry Ph. D. thesis, Indian Institute of Science, Bangalore
Rajasekar N and Soundararajan S 1981J. Inorg. Nucl. Chem. 43 977
Serra O A, Perrier M, Lakatas Osorio V K and Kawano Y 1976Inorg. Chim. Acta 17 135
Sinha S P 1966Spectrochim. Acta 22 57
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Navaneetham, N.S., Kalyanasundaram, R., Rajasekar, N. et al. Lanthanide perchlorate complexes of 2-acetamidopyridine-1-oxide. Proc. Indian Acad. Sci. (Chem. Sci.) 98, 161–164 (1987). https://doi.org/10.1007/BF02900714
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02900714