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The effect of cerium on high temperature tensile and creep behavior of a superalloy

  • Symposium on The Role of Trace Elements and Interfaces in Creep Failure
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Abstract

The presence of trace impurities such as S and O can cause embrittlement during elevated and high temperature deformation of iron or nickel-base alloys. In this study various amounts of Ce, ranging from 0 to 0.24 wt pct, have been added to an iron-nickel base superalloy, Udimet 901, in order to study its role in the refining process of S and O in the melt, hot workability, creep and stress rupture, and microstructure. It is found that Ce addition decreases the 0 and S content in the melt and improves both the hot workability and creep ductility. An optimum residual Ce content of 30 ppm was found for which ductilities are maximum. Higher residual cerium contents result in deleterious hot embrittlement. SEM as well as TEM/STEM microscopy combined with X-ray EDS spectroscopy were used to determine the inclusion content present in the alloy as well as the fine spatial microchemistries, especially at grain boundaries.

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References

  1. Interfacial Segregation, W. C. Johnson and J.M. Blakely, eds., ASM, Metals Park, OH, 1979.

    Google Scholar 

  2. E.D. Hondros and M. P. Seah:Int. Met. Rev., 1977, vol. 22, pp. 262–301.

    CAS  Google Scholar 

  3. R.T. Holt and W. Wallace:Int. Met. Rev., 1976, vol. 21, pp. 1–24.

    CAS  Google Scholar 

  4. M. G. Lozinskiy, G. M. Volkogon, and N.Z. Pertsowskiy:Russ. Met., 1967, vol. 5, p. 65.

    Google Scholar 

  5. G. H. Gessinger and M. J. Bomford:Int. Met. Rev., 1974, vol. 19, p. 51.

    CAS  Google Scholar 

  6. R.H. Bricknell and D. A. Woodford:Metall. Trans. A, 1981, vol. 12A, pp. 1673–80.

    Google Scholar 

  7. F. N. Darmara:Trans, of the Vacuum Metallurgy Conf., AVS, New York, NY, 1967, pp. 343–95.

    Google Scholar 

  8. W.E. Johnson and W.H. Sutton:Electric Furnace Proc, 1971, vol. 29, pp. 19–29.

    Google Scholar 

  9. W. G. Wilson, D. A. R. Kay, and A. Vahed:J. of Metals, May 1974, pp. 14-23.

  10. A. Vahed and D.A.R. Kay:Metall. Trans. B, 1976, vol. 7B, pp. 375–83.

    CAS  Google Scholar 

  11. P.E. Waudby:Int. Met. Rev., 1978, vol. 2, pp. 74–98.

    Google Scholar 

  12. R. E. Bailey, R. R. Shiring, and R. J. Anderson:Superalloys: Metallurgy and Manufacture, Proc. Third Int. Symp. on Superalloys, B. H. Kear, D.R. Muzyka, J.K. Tien, and S.T. Wlodek, eds., Claitors, Baton Rouge, LA, 1976, pp. 109–18.

    Google Scholar 

  13. J. E. Doherty, A. F. Giamei, and B. H. Kear:Can. Met. Quart., 1974, vol. 13, no. 1, pp. 229–36.

    CAS  Google Scholar 

  14. W. C. Johnson, J. E. Doherty, B. H. Kear, and A. F. Giamei:Scripta Met., 1974, vol. 8, pp. 971–74.

    Article  CAS  Google Scholar 

  15. Y. Nishi, H. Nomura, and K. Shiracani:Trans. ISIJ, 1975, vol. 15, pp. 531–39.

    Google Scholar 

  16. S. Yamaguchi, H. Kobagashi, T. Matsumiya, and S. Hayami:Metals Technology, May 1979, pp. 170-75.

  17. J. G. Cannon, R. S. Cremisio, and C. F. Elliott:Proc. Third lnt. Symp. ESR and Other Spec. Melt Tech., ASM, Metals Park, OH, 1971, part III, pp. 1–30.

    Google Scholar 

  18. T. V. Suistunova and G. V. Estulin:Stahl, 1963, vol. 9, pp. 725–28.

    Google Scholar 

  19. D. Li, F. Cosandey, G. E. Maurer, B. Foote, and J. K. Tien:Metall. Trans. B, 1982, vol. 13B, pp. 603–12.

    CAS  Google Scholar 

  20. K. A. Gschneider, N. Kippenhan, and O. D. McMasters: Report No. IS-R1C-6, Rare Earth Information Center, Ames, IA, 1973.

    Google Scholar 

  21. K. A. Gschneider and M.E. Verkade: Report No. IS-R1C-7, Rare Earth Information Center, Ames, IA, 1974.

    Google Scholar 

  22. L. A. Jackman and G. F. Boesche: unpublished research, Special Metals Corporation, New Hartford, NY.

  23. J. R. Rellick, C. J. McMahon, Jr., H. L. Marcus, and P. W. Palmberg:Metall. Trans., 1971, vol. 2, pp. 1492–94.

    CAS  Google Scholar 

  24. A.D. Donald:Phil. Mag., 1976, vol. 34, pp. 1185.

    CAS  Google Scholar 

  25. T. J. Headley, M. M. Karnowsky, and W. R. Sorenson:Metall. Trans. A, 1982, vol. 13A, pp. 345–53.

    CAS  Google Scholar 

  26. D. Muzyka:The Superalloys, C.T. Sims and W.C. Hagel, eds., John Wiley & Sons, 1972, pp. 113-43.

  27. M. Carroll, F. Cosandey, G. E. Maurer, and J. K. Tien: unpublished research, Columbia University, New York, NY.

  28. S.H. Goods and L.M. Brown:Acta Met., 1979, vol. 27, pp. 1–15.

    Article  CAS  Google Scholar 

  29. L.E. Swensson and G.L. Dunlop:Can. Met. Quarterly, 1979, vol. 18, p. 39.

    Google Scholar 

  30. L.E. Swensson and G.L. Dunlop:Int. Met. Rev., 1981, vol. 2, pp. 109–31.

    Article  Google Scholar 

  31. W. Pavinich and R. Raj:Metall. Trans. A, 1977, vol. 8A, pp. 1917–33.

    CAS  Google Scholar 

  32. W. D. Nix, K.S. Yu, and J. S. Wang:Metall. Trans. A, 1983, vol. 14A, p. 563.

    Google Scholar 

  33. F. Garofalo:Ductility, H.W. Paxton, ed., ASM, Metals Park, OH, 1968, pp. 87–132.

    Google Scholar 

  34. W. J. McG. Tegart:Ductility, H. W. Paxton, ed., ASM, Metals Park, OH, 1968, pp. 133–75.

    Google Scholar 

  35. T.A. Eingh and N. Lindskog:Scan. J. Metall., 1975, vol. 4, pp. 49–58.

    Google Scholar 

  36. M.P. Seah and E.D. Hondros:Proc. Roy. Soc. Lond., 1973, vol. A335, pp. 191–212.

    Google Scholar 

  37. D. L. Wood:Trans. TMS-AIME, 1957, vol. 209, p. 406.

    Google Scholar 

  38. D. J. Nesslage and L. S. Yu:Grain Boundaries in Engineering Materials, 4th Bolton Landing Conference, J. L. Walter, J. H. Westbrook, and D.A. Woodford, eds., Claitors, Baton Rouge, LA, 1974, pp. 115–25.

    Google Scholar 

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Formerly Research Associate, Henry Krumb School of Mines, Columbia University, New York, NY 10027.

This paper is based on a presentation made at the symposium “The Role of Trace Elements and Interfaces in Creep Failure” held at the annual meeting of The Metallurgical Society of AIME, Dallas, Texas, February 14-18, 1982, under the sponsorship of The Mechanical Metallurgy Committee of TMS-AIME.

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Cosandey, F., Li, D., Sczerzenie, F. et al. The effect of cerium on high temperature tensile and creep behavior of a superalloy. Metall Trans A 14, 611–621 (1983). https://doi.org/10.1007/BF02643777

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