Skip to main content
SpringerLink
Log in

Chemiluminescence and catalysis of decomposition of dispiro(diadamantane-1,2-dioxetane) in solutions of lanthanide perchlorates

2. Chemiluminescence of EuIII, TbIII, and PrIII

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Chemiluminescence (CL) accompanying the decomposition of dispiro(diadamantane-1,2-dioxetane) (1) in acetonitrile solutions of EuIII, GdIII, TbIII, PrIII, and CeIII perchlorates was studied. In the presence of EuIII, TbIII, and PrIII ions, the chemiluminescence spectra contain the luminescence bands of these ions. In the cases of GdIII and CeIII, the chemiluminescence is caused by deactivation of singlet-excited adamantanone (2). The excitation of the lanthanide ion depends on the existence of suitable energy levels at which intracomplex excitation transfer from the3n,π* of ketone is possible. Chemiluminescence of1 increases in solutions of EuIII and TbIII. The yields of CL and excitation of the lanthanide ions in the decomposition of1 in the1·EuIII and1\TbIII complexes were determined: φEu · =0.013 ± 0.003 and φTb · =0.08±0.02. The fact that the efficiency for the population of the5D4-level of TbIII is higher than that for the5D1 and5D0-levels of EuIII is related to the difference in the energy gap between the triplet level of2 and the excited levels of the lanthanides.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. P. Kazakov, A. I. Voloshin, S. S. Ostakhov, and I. A. Khusainova,Izv. Akad. Nauk, Ser. Khim., 1996, 2479 [Russ. Chem. Bull., 1996,45, 2350 (Engl. Transl.)].

    Google Scholar 

  2. R. Sh. Ableeva, L. M. Khalilov, V. P. Kazakov, and G. A. Tolstikov,Kinet. Katal., 1993,34, 811 [Kinet. Catal., 1993,34 (Engl. Transl.)].

    CAS  Google Scholar 

  3. N. Sh. Ableeva,Author’s Abstract, Ph. D. (Chem.) Thesis, Ufa, 1995 (in Russian).

  4. P. D. Bartlett, A. L. Baumstark, and M. E. Landis,J. Am. Chem. Soc., 1974,96, 5552.

    Article  Google Scholar 

  5. P. D. Bartlett and J. S. McKennis,J. Am. Chem. Soc., 1977,99, 5334.

    Article  CAS  Google Scholar 

  6. A. I. Voloshin, G. L. Sharipov, V. P. Kazakov, and G. L. Tolstikov,Izv. Akad. Nauk, Ser. Khim., 1992, 1056 [Bull. Russ. Akad. Sci., Div. Chem. Sci., 1992,41, 818 (Engl. Transl.)].

    Google Scholar 

  7. W. R. Dawson and J. L. Kropp,J. Opt. Am. Soc., 1965,55, 822.

    Article  CAS  Google Scholar 

  8. G. B. Schuster, N. J. Turro, H.-C. Steinmetzer, A. P. Schaap, G. Faler, W. Adam, and J. C. Liu,J. Am. Chem. Soc., 1975,97, 7110.

    Article  CAS  Google Scholar 

  9. G. L. Sharipov, A. I. Voloshin, V. P. Kazakov and G. A. Tolstikov,Dokl. Akad. Nauk SSSR, 1990,315, 425 [Dokl. Chem., 1990,315 (Engl. Transl.)].

    CAS  Google Scholar 

  10. V. L. Ermolaev, E. B. Sveshnikova, and T. A. Shakhverdov,Usp. Khim., 1976,35, 1753 [Russ. Chem. Rev., 1976,35 (Engl. Transl.)].

    Google Scholar 

  11. D. C. Doetschman, J. L. Fish, P. Lechtken, and D. Negus,Chem. Phys., 1980,51, 89.

    Article  CAS  Google Scholar 

  12. G. Stein and E. Wurzberg,J. Chem. Phys., 1975,62, 208.

    Article  CAS  Google Scholar 

  13. G. J. Kavarnos and N. J. Turro,Chem. Rev., 1986,86, 401.

    Article  CAS  Google Scholar 

  14. T. Wilson,J. Photochem. Photobiol., 1979,30, 177.

    CAS  Google Scholar 

  15. G. A. Tolstikov, G. L. Sharipov, A. I. Voloshin, S. S. Ostakhov, and V. P. Kazakov,Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 787 [Bull. Akad. Sci. USSR, Div. Chem. Sci., 1986,35, 715 (Engl. Transl.)].

    Google Scholar 

  16. D. R. Charney, J. C. Dalton, R. R. Hautala, J. J. Snyder, and N. J. Turro,J. Am. Chem. Soc., 1974,96, 1407.

    Article  CAS  Google Scholar 

  17. N. Sh. Ableeva, A. I. Voloshin, S. S. Ostakhov, A. G. Kukovinets, V. N. Korobeinikova, and V. P. Kazakov,Izv. Akad. Nauk, Ser. Khim., 1994, 1762 [Russ. Chem. Bull., 1994,43, 1664 (Engl. Transl.)].

  18. W. H. Richardson, J. H. Burns, and M. E. Price,J. Am. Chem. Soc., 1978,100, 7596.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    V. P. Kazakov, A. I. Voloshin, S. S. Ostakhov, I. A. Khusainov & E. V. Zharinova

Authors
  1. V. P. Kazakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Voloshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. S. Ostakhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. A. Khusainov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. V. Zharinova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

For Part I, see Ref. 1.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 730–735, April, 1997.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kazakov, V.P., Voloshin, A.I., Ostakhov, S.S. et al. Chemiluminescence and catalysis of decomposition of dispiro(diadamantane-1,2-dioxetane) in solutions of lanthanide perchlorates. Russ Chem Bull 46, 699–704 (1997). https://doi.org/10.1007/BF02495197

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02495197

Key words

Search

Navigation