Summary
A simultaneous capillary Gas Chromatographic-Mass Spectrometric (GC-MS) method is described for the determination of thirteen pesticides belonging to the triazine and amide families in water. The sample is extracted in liquid-liquid mode (dichloromethane) and then the determination of the residues is carried out by capillary gas chromatography with mass spectrometric detection in the Selected-Ion Monitoring mode (SIM). The average recoveries of spiked compounds are in the 78.4–135.4% range between the relative low level (0.100 μg L−1) and the relative high level (10.0 μg L−1). The limits of detection (LOD) are in the 0.009–0.128 μg L−1 range.
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References
F. Rouberty, J. Fournier, Chromatographia41, 553 (1995).
A. E. Smith, D. C. G. Muir, R. Grover, in Analysis of Pesticides in Water A. S. Y. Chau, B. K. Afghan and J. W. Robinson, Eds., CRC Press, Boca Raton, Florida, USA,3, 213 (1982).
H. Sabik, S. Cooper, P. Lafrance, J. Fournier, Talanta42, 717 (1995).
J. J. Vreuls, A. J. H. Louter, U. A. Z. Brinkman in Analysis of Pesticides in Ground and Surface Water II, H.-J. Stan and W. Ebing, Eds., Chemistry of Plant Protection,12, Springer-Verlag, Berlin, Heidelberg, Germany, 1 (1995).
P. T. Holland, in Analysis of Pesticides in Ground and Surface Water I, H.-J. Stan and W. Ebing, Eds., Chemistry of Plant Protection11, Springer-Verlag, Berlin, Heidelberg, Germany, 67 (1995).
J. M. Warner, D. D. Arras, in Comprehensive Analytical Profiles of Important Pesticides, J. Sherma and T. Cairns, Eds., CRC Press, Boca Raton, Florida, USA, 109 (1993).
K. A. Ramsteiner, W. D. Hormann, D. O. Eberle, J. Assoc. Off. Anal. Chem.57, 192 (1974).
M. Psathaki, E. Manoussaridou, E. G. Stephanou, J. Chromatogr. A667, 241 (1994).
Pesticides in Ground and Surface Water, H. Börner, Ed., Chemistry of Plant Protection9, Springer-Verlag, Berlin Heidelberg, Germany, 1 (1994).
H.-J. Stan, in Analysis of Pesticides in Ground and Surface Water I, H.-J. Stan and W. Ebing, Eds., Chemistry of Plant Protection11, Springer-Verlag, Berlin Heidelberg, Germany, 113 (1995).
H.-J. Stan, T. Heberer, in Analysis of Pesticides in Ground and Surface Water I, H.-J. Stan and W. Ebing Eds., Chemistry of Plant Protection11, Springer-Verlag, Berlin Heidelberg, Germany, 141 (1995).
K Pfleger, H. H. Maurer, A. Weber, Mass Spectra and GC Data, VCH, Weinheim, Germany, parts 1, 2 and 3 (1992).
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Hu, R., Berthion, J.M., Bodereau, I. et al. Simultaneous capillary GC-MS determination of triazines and amides in water. Chromatographia 43, 181–186 (1996). https://doi.org/10.1007/BF02292948
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DOI: https://doi.org/10.1007/BF02292948