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Analytical expressions for the retention volume in gas adsorption chromatography

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Summary

It has been shown that the experimentally obtained function — retention volume VN vs pressure p — approximates the exponential higher degree polynomial very well. The possibilities of utilizing this approximation in the determination of energetic heterogeneity of adsorbents, in calculating adsorption isotherms and the gas-solid virial coefficients are shown. The experimentally obtained functions VN(p) for the adsorption of n-hexane and 1-hexene on controlled porosity glass serve to illustrate theoretical considerations.

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Authors and Affiliations

  1. Department of Physical Chemistry, Institute of Chemistry UMCS, Nowotki 12, 20031, Lublin, Poland

    Z. Suprynowicz, M. Jaroniec & J. Gawdzik

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  1. Z. Suprynowicz
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  2. M. Jaroniec
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  3. J. Gawdzik
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Suprynowicz, Z., Jaroniec, M. & Gawdzik, J. Analytical expressions for the retention volume in gas adsorption chromatography. Chromatographia 9, 161–167 (1976). https://doi.org/10.1007/BF02281663

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