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CGC/AED and CGC/ECD/NPD comparison for the determination of acaricides in honey after hexane/acetone extraction

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Summary

The performance of a gas chromatographic system coupled to an atomic emission detector (GC/AED) is tested by comparison with a two-dimensional gas chromatographic system equipped with capillary columns of different polarity and simultaneous electron capture and nitrogen-phosphorus detection (ECD/NPD), for the determination of the acaricides chlordimeform, bromopropylate, amitraz and coumaphos on spiked honey samples. The acaricides were extracted with ann-hexane/acetone mixture (80∶20, v/v) with a further clean-up step on an octadecylsilane cartridge. The 193 nm carbon emission line is the best choice in terms of sensitivity whereas the ECD/NPD system gives better selectivity.

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Authors and Affiliations

  1. Department of Analytical Chemistry. Faculty of Sciences, University of Valladolid, Prado de la Magdalena, 47005, Valladolid, Spain

    J. J. Jiménez & J. L. Bernal

  2. Servicio de Investigación Agraria, Junta de Castilla y León, P.O. Box 172, 47080, Valladolid, Spain

    J. Atienza

Authors
  1. J. J. Jiménez
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  2. J. L. Bernal
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  3. J. Atienza
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Jiménez, J.J., Bernal, J.L. & Atienza, J. CGC/AED and CGC/ECD/NPD comparison for the determination of acaricides in honey after hexane/acetone extraction. Chromatographia 42, 130–134 (1996). https://doi.org/10.1007/BF02269641

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  • DOI: https://doi.org/10.1007/BF02269641

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