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Effect of the water of crystallization on the Mössbauer spectra of hexacyanoferrates (II and III)

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Abstract

Mössbauer spectra were recorded on hydrated, dehydrated and rehydrated hexacyanoferrate (II and III) samples including alkaline, alkaline-earth, transition metal and rare-earth salts. The location of the water molecules around the complex hexacyanoferrate anion has a decisive role on the quadrupole splitting of the low-spin FeIII cation.

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References

  1. N.N. Greenwood and T.C. Gibb,Mössbauer Spectroscopy (Chapman and Hall, London, 1971) p. 91.

    Google Scholar 

  2. E. Reguera, J.F. Bertrán, A. Dago, C. Díaz, J. Blanco and S. Rondon, Hyp. Int. 53 (1990) 391.

    Google Scholar 

  3. E. Reguera, J.F. Bertrán, C. Díaz and J. Molerio, Hyp. Int. 73 (1992) 285.

    Google Scholar 

  4. E. Reguera, J.F. Bertrán and J. Duque, Polyhedron 1993, accepted.

  5. T.C. Yang and W.C. Neely, Anal. Chem. 58 (1986) 1551.

    Google Scholar 

  6. W.E. Bailey, R.J. Williams and W.O. Milligan, Acta Cryst. B 29 (1973) 1365.

    Google Scholar 

  7. X.L. Xu, R.E. Emmenegger and F. Hulliger, Eur. J. Solid State Inorg. Chem. 27 (1990) 537.

    Google Scholar 

  8. F. Hulliger, M. Landolt and H. Vetsch, J. Solid State Chem. 18 (1976) 283.

    Google Scholar 

  9. W. Petter, V. Gramlich, F. Hulliger and H. Vetsch, Eur. J. Solid State Inorg. Chem. 29 (1992) 65.

    Google Scholar 

  10. D.F. Mullica, E.L. Sappenfield and H.O. Perkins, J. Solid State Chem. 73 (1988) 65.

    Google Scholar 

  11. A. Ludi and H.U. Güdel, Structure Bonding 14 (1973) 1.

    Google Scholar 

  12. J.B. Ayres and W.H. Waggoner, J. Inorg. Nucl. Chem. 33 (1971) 721.

    Google Scholar 

  13. A.Z. Hrinkiewicz, B.D. Sawicka and J.A. Sawicki, Phys. Stat. Sol. 38 (1970) K111.

    Google Scholar 

  14. A.F. Green Jr. and M.M. Chamberlain, J. Inorg. Nucl. Chem. 25 (1963) 1471.

    Google Scholar 

  15. D. Raj and J. Danon, J. Inorg. Nucl. Chem. 37 (1975) 2039.

    Google Scholar 

  16. M. Rüegg, A. Ludi and K. Rieder, Inorg. Chem. 10 (1971) 1773.

    Google Scholar 

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Authors and Affiliations

  1. National Center for Scientific Research, PO Box 6990, Havana, Cuba

    E. Reguera & J. Fernández-Bertrán

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  1. E. Reguera
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  2. J. Fernández-Bertrán
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Reguera, E., Fernández-Bertrán, J. Effect of the water of crystallization on the Mössbauer spectra of hexacyanoferrates (II and III). Hyperfine Interact 88, 49–58 (1994). https://doi.org/10.1007/BF02068701

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  • DOI: https://doi.org/10.1007/BF02068701

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