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Reaktionen von Glyoxal mit Glycin I. Mitteilung Untersuchungen der gebildeten Schiffschen Base

Reactions of glyoxal with glycine I. Study of the schiff base formed by reaction of glyoxal with glycine

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Summary

Glycine reacts in aqueous solutions only with one carbonyl group of glyoxal. The equilibrium:

was investigated by polarography. The equilibrium constant of this reaction and the formation of protonized imine form:

were measured. Changes of the ultraviolet absorption show the presence of the compound -N=CH-COOH in absence of oxygen and the formation of pyrazine in presence of oxygen.

Zusammenfassung

Glycin reagiert in Wasser nur mit einer Carbonylgruppe des Glyoxals. Das Gleichgewicht:

wurde polarographisch nachgewiesen. Die Gleichgewichtskonstante dieser Reaktion and die Bildung der protonisierten Iminform:

wurden gemessen. Die Veränderungen der Ultraviolettabsorption zeigen die Gegenwart der Verbindung -N=CH-COOH in sauerstofffreiem und die Bildung von Pyrazin in sauerstoffhaltigem Milieu.

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Authors and Affiliations

  1. Institut für Lebensmittelchemie Chemisch-technologische Hochschule, Dejvice, Suchbatarova 1905, 6, Praha

    J. Velíšek, J. Davídek, J. Pokorný, S. Klein & G. Janíček

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  1. J. Velíšek
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  2. J. Davídek
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  3. J. Pokorný
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  4. S. Klein
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  5. G. Janíček
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Velíšek, J., Davídek, J., Pokorný, J. et al. Reaktionen von Glyoxal mit Glycin I. Mitteilung Untersuchungen der gebildeten Schiffschen Base. Z Lebensm Unters Forch 149, 69–74 (1972). https://doi.org/10.1007/BF01856618

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  • DOI: https://doi.org/10.1007/BF01856618

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