Abstract
The phase diagram of (NaCN)1−x(KCN)x was examined by neutron powder diffraction in the temperature range 5K ≦T≦300 K. Several non-cubic low-temperature phases were identified for concentrationsx<x c1=0.15 andx≧x c2=0.89. Lattice parameters and ferroelastic deformations were determined from the observed powder patterns. The phase transformations were characterized following the temperature dependence of the appropriate order parameters.
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Lüty, F.: Defects in insulating crystals. Turkevitch, V.M., Swartz, K.K. (eds.), pp. 69–89. Berlin, Heidelberg, New York: Springer 1981
Michel, K.H., Naudts, J.: J. Chem. Phys.68, 216 (1977)
Suga, H., Matsuo, T., Seki, S.: Bull. Chem. Soc. Jpn.38, 1115 (1965) Matsuo, T., Suga, H., Seki, W.: Bull. Chem. Soc. Jpn.41, 583 (1968)
Verwell, H.J., Bijvoet, J.M.: Z. Krist.100, 201 (1938)
Bijvoet, J.M., Lely, J.A.: Rec. Trav. Chim. Pays-Bas59, 908 (1940)
Fontaine, D.: C. R. Acad. Sc. Paris281, 443 (1975)
Rowe, J.M., Rush, J.J., Prince, E.: J. Chem. Phys.66, 5147 (1977)
Santos, R.R. dos, Koiller, B., Weid, J.P. von der, Costa Ribeiro, S., Chaves, A.S., Sà Barreto, F.C.: J. Phys. C11, 4557 (1978)
Pirc, R., Vilfan, I.: Solid State Commun.39, 181 (1981)
Koiller, B., Davidovich, M.A., Scavarda do Carmo, L.C., Lüty, F.: Phys. Rev. B29, 3586 (1984)
Ohno, E.: J. Phys. Soc. Jpn.57, 4265 (1988)
Knorr, K., Loidl, A.: Phys. Rev. B31, 5387 (1985)
Loidl, A., Schräder, T., Knorr, K., Böhmer, R., Mertz, B., McIntyre, G.J., Vogt, T., Mutka, H., Müllner, M., Jex, H., Haussühl, S.: Z. Phys. B — Condensed Matter75, 81 (1989)
Rowe, J.M., Bouillot, J., Rush, J.J., Lüty, F.: Physica B136, 498 (1986)
Bourson, P.G., Gorczyca, G., Durand, D.: Cryst. Latt. Def. Amorph. Mater16, 311 (1987)
Civera Garcia, E., Knorr, K., Loidl, A.: Phys. Rev. B36, 8517 (1987)
Bouillot, J., Soubeyroux, J.L., Lüty, F.: Physica B156 &157, 81 (1989)
Elschner, S., Knorr, K., Loidl, A.: Z. Phys. B — Condensed Matter60, 209 (1985)
Jäckle, J.: Rep. Prog. Phys.49, 171 (19860
Behnke, G., Biltz, H., Büttner, H.: Phys. Rev. Lett.56, 1276 (1986)
Michel, K.H.: Z. Phys. B — Condensed Matter68, 259 (1987)
Lewis, L., Klein, M.L.: Phys. Rev. Lett.57, 2698 (1986) Lewis, L., Klein, M.L.: J. Phys. Chem.91, 4990 (1987)
Fossum, J.O., Garland, C.W., Wells, A.: Preprint (1987)
Ortiz Lopez, J.: Ph. D. Thesis, University of Utah, 1983; Lüty, F., Ortiz Lopez, J.: Phys. Rev. Lett.50, 1289 (1983)
Schräder, T., Loidl, A., Vogt, T.: Phys. Rev. B39, 6186 (1989)
Loidl, A., Schräder, T., Böhmer, R., Knorr, K., Kjems, J.K., Born, R.: Phys. Rev. B34, 1238 (1986)
Gerward, L., Staun Olsen, J., Benedict, U.: Physica B144, 72 (1986)
Schräder, T., Loidl, A., Vogt, T.: Ferroelectrics (in press)
Knopp, G., Knorr, K., Loidl, A., Haussühl, S.: Z. Phys. B —Condenset Matter51, 259 (1983)
Knorr, K., Civera Garcia, E., Loidl, A.: Phys. Rev. B35, 4998 (1987)
Pawley, G.S.: J. Appl. Crystallogr.14, 357 (1981)
Aizu, K.: J. Phys. Soc.28, 706 (1970)
Rehwald, W., Sandercock, J.R., Rossinelli, M.: Phys. Status Solidi A42, 699 (1977)
Hessinger, J., Knorr, K.: Phys. Rev. Lett.63, 2749 (1989)
Dultz, W.: J. Chem. Phys.65, 2812 (1976)
Stokes, H.T., Swinney, R.D.: Phys. Rev. B31, 7133 (1985)
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Schräder, T., Loidl, A. & Vogt, T. Phases and phase transitions in the mixed molecular system (NaCN)1−x(KCN)x . Z. Physik B - Condensed Matter 79, 423–430 (1990). https://doi.org/10.1007/BF01437653
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DOI: https://doi.org/10.1007/BF01437653