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Investigation of radical pairs produced upon pulse action of elastic waves on the 3,6-di-tert-butylcatechol-3,6-di-tert-butyl-o-benzoquinone-sulfur system

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The pulse action of elastic waves on polycrystalline mixtures of 3,6-di-tert-butylcatechol and 3,6-di-tert-butyl-o-benzoquinone produces radical pairs stable at room temperature, and the addition of polycrystalline sulfur considerably increases their yield. The dependences of formation and decay rates of paramagnetic centers on the composition of the mixture were studied. The threshold character of formation of paramagnetic centers at various powers of elastic wave pulse was established.

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Authors and Affiliations

  1. Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    A. I. Aleksandrov & I. Yu. Metlenkova

  2. A. N. Nesmeyanov Institute of Otganoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. I. Prokof'ev & N. N. Bubnov

  3. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    G. D. Perekhodtsev, D. S. Tipikin, S. D. Chemerisov & Ya. S. Lebedev

Authors
  1. A. I. Aleksandrov
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  2. A. I. Prokof'ev
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  3. I. Yu. Metlenkova
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  4. N. N. Bubnov
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  5. G. D. Perekhodtsev
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  6. D. S. Tipikin
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  7. S. D. Chemerisov
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  8. Ya. S. Lebedev
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriva Khimicheskaya, No. 4, pp. 864–868, April, 1996.

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Aleksandrov, A.I., Prokof'ev, A.I., Metlenkova, I.Y. et al. Investigation of radical pairs produced upon pulse action of elastic waves on the 3,6-di-tert-butylcatechol-3,6-di-tert-butyl-o-benzoquinone-sulfur system. Russ Chem Bull 45, 819–823 (1996). https://doi.org/10.1007/BF01431304

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  • DOI: https://doi.org/10.1007/BF01431304

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