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Y(Er)-doped tetragonal zirconia polycrystalline solid electrolyte

Part 3 Electrical properties

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Abstract

The electrical conductivity of fully dense bodies of polycrystalline tetragonal zirconia (TZP) in the composition range 2 to 3 mol % Y2O3 (Er2O3) was measured. Throughout this work, a.c. impedance complex plane analysis was used. From this method grain-interior and grain-boundary conductivity contributions were obtained separately. Plots of conductivity against reciprocal temperature of both contributions were evaluated. An electrode-electrolyte interphase conductivity contribution was detected and considered. The influence of impurities, and ageing behaviour was also studied. The activation, migration and association energies were estimated and discussed on the basis of up-to-date theoretical and structural information.

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References

  1. P. Durán, P. Recio, J. R. Jurado, C. Pascual andC. Moure,J. Mater. Sci. 23 (1988) 0000.

    Google Scholar 

  2. P. Durán, P. Recio, J. R. Jurado, C. Pascual, F. Capel andC. Moure,ibid. 23 (1988) 0000.

    Google Scholar 

  3. T. K. Gupta, R. B. Grekila andE. C. Subbarao,J. Electrochem. Soc. 128 (1981) 929.

    Google Scholar 

  4. N. Bonanos, R. K. Slotwinski, B. C. H. Steele andE. P. Butler,J. Mater. Sci. Lett. 3 (1984) 245.

    Google Scholar 

  5. C. Mocure, J. R. Jurado, P. Durán, Proceedings of the British Ceramic Society no. 36, “Electric Ceramics”, edited by B. C. H. Steele (Stoke-on-Trent, UK) (1985) p. 31.

    Google Scholar 

  6. K. Keizer, M. Van Hemert, M. A. C. G. Van De Graaf andA. J. Burggraaf,Solid State Ionics 16 (1985) 67.

    Google Scholar 

  7. J. R. Jurado, C. Moure andP. Durán, in “Proceedings of the 6th Riso International Symposium, Roskilde, Denmark, September 1985”, edited by F. W. Poulsenet al. (Odense, Denmark, 1985) p. 305.

  8. J. R. Jurado, C. Moure andP. Durán,Physique 47 (1986) C1–789.

    Google Scholar 

  9. K. Keizer, M. Van Hemert, A. J. A. Winnubst, M. A. C. G. van DeGraaf andA. J. Burggraaf,ibid. 47 (1986) C1–783.

    Google Scholar 

  10. M. Weller andH. Schubert,J. Amer. Ceram. Soc. 69 (1986) 573.

    Google Scholar 

  11. C. Pascual, C. Moure, J. R. Jurado andP. Durán, in “High Tech Ceramics”, edited by Vincenzini (Elsevier, Amsterdam, 1987) p. 1915.

    Google Scholar 

  12. T. Sato andM. Schimada,J. Mater. Sci. 20 (1985) 3988.

    Google Scholar 

  13. Idem, Amer. Ceram. Soc. Bull. 64 (1985) 1382.

    Google Scholar 

  14. K. Tsukuma andM. Shimada,J. Mater. Sci. 20 (1985) 1178.

    Google Scholar 

  15. P. Duwez andF. Odell,J. Amer. Ceram. Soc. 33 (1950) 274.

    Google Scholar 

  16. E. Tani, M. Yoshimura andS. Somiya,ibid. 66 (1983) 506.

    Google Scholar 

  17. J. E. Bauerle,J. Phys. Chem. Solids 30 (1969) 2657.

    Google Scholar 

  18. C. M. Mari,Solid State Ionics 12 (1984) 419.

    Google Scholar 

  19. H. J. Won, S. H. Park, K. H. Kim andJ. S. Choi,J. Phys. Chem. Solids 48 (1987) 383.

    Google Scholar 

  20. N. Bonanos, R. K. Slotwinski, B. C. H. Steele andE. P. Butler,J. Mat. Sci. 19 (1984) 785.

    Google Scholar 

  21. S. Ikeda, O. Sakurai, K. Uematsu, N. Mizutani andM. Kato,J. Mater. Sci. 20 (1985) 4593.

    Google Scholar 

  22. A. N. Cormack, in Proceedings 6th Riso International Symposium, Roskilde, Denmark, September 1985, edited by F. W. Poulsenet al., Odense, Denmark, 1985, p. 11.

  23. A. N. Cormack, in “High Tech Ceramics”, edited by P. Vincenzini, (Amsterdam, 1987) p. 351.

  24. J. E. Bauerle andJ. Hrizo,J. Phys. Chem. Solids 30 (1969) 565.

    Google Scholar 

  25. J. A. Kilner andB. C. H. Steele, in “Non stoichiometric oxides”, edited by O. T. Sorensen (Academic, New York, 1981) p. 233.

    Google Scholar 

  26. B. Cales andJ. F. Baumard,Rev. Int. Hautes Temp. Refract. 17 (1980) 137.

    Google Scholar 

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Authors and Affiliations

  1. Departamento de Materiales Cerámicos Especiales, Instituto de Cerámica y Vidrio (CSIC), Atrganda del Rey, Madrid, Spain

    P. Durán, P. Recio, J. R. Jurado, C. Pascual, M. T. Hernandez & C. Moure

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  1. P. Durán
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  2. P. Recio
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  3. J. R. Jurado
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  4. C. Pascual
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  5. M. T. Hernandez
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  6. C. Moure
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Durán, P., Recio, P., Jurado, J.R. et al. Y(Er)-doped tetragonal zirconia polycrystalline solid electrolyte. J Mater Sci 24, 717–725 (1989). https://doi.org/10.1007/BF01107465

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  • DOI: https://doi.org/10.1007/BF01107465

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