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Leveling of reactivity for intramolecular radical substitution reactions in viscous media

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Abstract

A leveling of the reactivity was found for intramolecular radical reactions in substituted 2-oxyphenoxyls in viscous media. A comparison of rate constants in toluene, hexane, pentane, and vaseline oil shows that fast reactions are decelerated more rapidly than slow reactions.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    R. R. Rakhimov & Ya. S. Lebedev

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. I. Prokof'ev

Authors
  1. R. R. Rakhimov
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  2. A. I. Prokof'ev
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  3. Ya. S. Lebedev
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 334–336, February, 1994.

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Rakhimov, R.R., Prokof'ev, A.I. & Lebedev, Y.S. Leveling of reactivity for intramolecular radical substitution reactions in viscous media. Russ Chem Bull 43, 313–315 (1994). https://doi.org/10.1007/BF00695840

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  • DOI: https://doi.org/10.1007/BF00695840

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