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Syntheses of diblock copolymers: poly(2-methylpropene)-b-poly(α-amino acid)

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Summary

Diblock copolymer poly (2-methylpropene)-b-poly (α-amino acid) was obtained by polymerization of the corresponding N-caboxy anhydride initiated by a poly (2-methylpropene) bearing a terminal amine in dioxane/CH2Cl2 mixture. Copolymers were analyzed by FT IR, 1H and 13C NMR. \(\overline M \) of the α-amino acid segment determined by 1H NMR fits well with those obtained by a theoretical calculation.

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Reference

  1. A. Nakajima, K. Kugo, T. Hayashi and H. Sato, Biomedical Polymers; Polymeric Materials and Pharmaceuticals for Biomedical Use, Edited by E. P. Goldberg and A. Nakajima, Academic Press, (1980).

  2. Ph. Degée, Ph. Dubois, R. Jérôme and Ph. Teyssié, Macromolecules, 25, 4242, (1992).

    Google Scholar 

  3. Ph. Degée, Ph. Dubois, R. Jérôme and Ph. Teyssié, J. Polym. Sci., part A, Polym. Chem., 31, 275, (1993).

    Google Scholar 

  4. B. Rajabalitabar, thèse de doctorat de l'UPMC, Paris (1992).

  5. C. H BAMFORD, H. BLOCK, Carboanhydrides, High Polymers, vol. XXVI Cyclic Monomers, edited by K. C. FRISCH, Wiley-Interscience, New York, (1972), chapter 7, pp. 687–749.

    Google Scholar 

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Authors and Affiliations

  1. Laboratoires de Synthèse Macromoléculaire et de Chimie Macromoléculaire associés au CNRS (URA 24), Université P. et M. Curie, 4, Place Jussieu, F-75252, Paris, France

    Chuong Bui, Hung Anh Nguyen & Hikaru Sekiguchi

  2. Université d'Evry Val d'Essonne, LPCB/CNRS, 2, Rue Henri Dunant, BP 28, F-94320, Thiais, France

    Hervé Cheradame

Authors
  1. Chuong Bui
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  2. Hung Anh Nguyen
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  3. Hikaru Sekiguchi
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  4. Hervé Cheradame
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Bui, C., Nguyen, H.A., Sekiguchi, H. et al. Syntheses of diblock copolymers: poly(2-methylpropene)-b-poly(α-amino acid). Polymer Bulletin 33, 37–42 (1994). https://doi.org/10.1007/BF00313471

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  • DOI: https://doi.org/10.1007/BF00313471

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