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Recent advances in styrene polymerization

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Polymer Synthesis

Part of the book series: Advances in Polymer Science ((POLYMER,volume 111))

Abstract

Over 200 references describing spontaneous, and chemically initiated styrene polymerization chemistry are reviewed with special emphasis on advances taking place in the past decade. The review is limited to chemistry useful for making amorphous high molecular weight polystyrene in solution polymerization processes. Chemical initiators have been categorized into three basic groups as follws: 1) anionic; 2) mono-radical; and 3) diradical. Analytical techniques used for determination of free radical polymerization kinetics and mechanisms are also discussed.

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Abbreviations

FR:

free radical

S:

styrene

PS:

polystyrene

A− :

active anion concentration

EB:

ethylbenzene concentration

EB− :

ethylbenzene anion concentration

H+C−1 :

contaminant concentration

[H+C−1]:

contaminant concentration in feed

I:

initiator concentration

Io :

initiator concentration in feed

I− :

initiator anion

Ct :

chain transfer constant

kcts :

rate constant for chain transfer to ethylbenzene

ki :

rate constant of n-butyl lithium initiation

kp :

rate constant of polystyrene propagation

kt :

rate constant of termination

ktic :

rate constant of contaminant reacting with initiator

ktpc :

rate constant of contaminant terminating anion

ktt :

rate constant of thermal termination of anions

Li+ :

lithium cation concentration

Mn :

number average molecular weight

PS:

terminated polystyrene concentration

PS− :

growing polystyrene anion concentration

Rcts :

rate of chain transfer to ethylbenzene

Ri :

rate of n-butyl lithium initiation

Rp :

rate of polystyrene propagation

Rt :

rate of anion termination

S:

styrene monomer concentration

S0 :

styrene monomer concentration in feed

Q:

residence time in CSTR

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Priddy, D.B. (1994). Recent advances in styrene polymerization. In: Polymer Synthesis. Advances in Polymer Science, vol 111. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0024127

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  • DOI: https://doi.org/10.1007/BFb0024127

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-57198-8

  • Online ISBN: 978-3-540-47949-9

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