Abstract
In this study, spatial and seasonal variations of water quality in Haraz River Basin were evaluated using multivariate statistical techniques, such as cluster analysis, principal component analysis and factor analysis. Water quality data collected from 8 sampling stations in river during 4 seasons (Summer and Autumn of 2007, Winter and Spring of 2008) were analyzed for 10 parameters (dissolved oxygen, Fecal Coliform, pH, water temperature, biochemical oxygen demand, nitrate, total phosphate, turbidity, total solid and discharge). Cluster analysis grouped eight sampling stations into three clusters of similar water quality features and thereupon the whole river basin may be categorized into three zones, i.e. low, moderate and high pollution. The principle component analysis/factor analysis assisted to extract and recognize the factors or origins responsible for water quality variations in four seasons of the year. The natural parameters (temperature and discharge), the inorganic parameter (total solid) and the organic nutrients (nitrate) were the most significant parameters contributing to water quality variations for all seasons. Result of principal component analysis and factor analysis evinced that, a parameter that can be significant in contribution to water quality variations in river for one season, may less or not be significant for another one.
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Abdul-Wahab, S. A.; Bakheit, C. S.; Al-Alawi, S. M., (2005). Principal component and multiple regression analysis in modelling of ground-level ozone and factors affecting its concentrations. Environ. Model. Softw., 20 (10), 1263–1271 (9 pages).
APHA, (1998). Standard methods for the examination of water and wastewater. American Public Health Association, 18th. Ed., Washington DC., USA.
Bengraine, K.; Marhaba, T. F., (2003). Using principal component analysis to monitor spatial and temporal changes in water quality. J. Hazard. Mater., 100 (1-3), 179–195 (17 pages).
Bricker, O. P.; Jones, B. F., (1995). Main factors affecting the composition of natural waters. In: Salbu, B., Steinnes, E. (Eds.), Trace Elements in Natural Waters. CRC Press, Boca Raton, FL, 1–5.
Clesceri, L. S.; Greenberg, A. E.; Eaton, A. D., (1998). Standard Methods for the Examination of Water and Wastewater, 20th. Ed., American Public Heath Association (APHA), American Water Works Association (AWWA) and Water Environment Federation (WEF), Washington, DC.
Dixon, W.; Chiswell, B., (1996). Review of aquatic monitoring program design. Water Res., 30 (9), 1935–1948 (14 pages).
Easton, Z. M.; Gerardmarchant, P.; Walter, M. T.; Petrovic, A. M.; Steenhuis, T. S., (2007). Identifying dissolved phosphorus source areas and predicting transport from an urban watershed using distributed hydrologic modeling. Water Resour. Res., 43 (11), 1–16 (16 pages).
Gross, B.; Montgomery-Brown, J.; Naumann A.; Reinhard M., (2004). Occurrence and fate of pharmaceuticals and alkyphenol ethoxylate metabolites in an effluent-dominated river and wetland. Environ. Toxicol. Chem., 23 (9), 2074–2083 (10 pages).
Helena, B.; Pardo, R.; Vega, M.; Barrado, E.; Ferna’ndez, J. M.; Ferna’ndez, L., (2000). Temporal evolution of groundwater composition in an alluvial aquifer (Pisuerga River, Spain) by principal component analysis. Water Res., 34 (3), 807–816 (10 pages).
Jarvie, H. P.; Whitton, B. A.; Neal, C., (1998). Nitrogen and phosphorus in east coast British rivers: Speciation, sources and biological significance. Sci. Total Environ., 210–211, 79–109 (31 pages).
Karbassi, A. R.; Nouri, J.; Ayaz, G. O., (2007). Flocculation of Cu, Zn, Pb, Ni and Mn during mixing of Talar River water with Caspian Seawater. Int. J. Environ. Res., 1 (1), 66–73 (8 pages).
Karbassi, A. R.; Nouri, J.; Mehrdadi, N.; Ayaz, G. O., (2008). Flocculation of heavy metals during mixing of freshwater with Caspian Sea water. Environ. Geol., 53 (8), 1811–1816 (6 pages).
Kazi, T. G.; Arain, M. B.; Jamali, M. K.; Jalbani, N.; Afridi, H. I.; Sarfraz, R. A.; Baig, J. A.; Shah, A. Q., (2009). Assessment of water quality of polluted lake using multivariate statistical techniques: A case study. Ecotox. Environ. Safe., 72 (20), 301–309 (9 pages).
Keramat Amirkolaie, A., (2008). Environmental impact of nutrient discharged by Aquaculture waste water on the Haraz River. J. Fish. Aqua. Sci., 3 (5), 275–279 (5 pages).
Khadka, R. B.; Khanal, A. B., (2008). Environmental Management Plan (EMP) for Melamchi water supply project, Nepal. Environ. Monitor. Assess., 146 (1-3), 225–234 (10 pages).
Kim, J. H.; Kim, R. H.; Lee, J.; Cheong, T. J.; Yum, B. W.; Chang, H. W., (2005). Multivariate statistical analysis to identify the major factors governing groundwater quality in the coastal area of Kimje, South Korea. Hydrol. Proc., 19 (6), 1261–1276 (16 pages).
Kinzelman, J.; Ng, C.; Jackson, E.; Gradus, S.; Bagley, R., (2003). Enterococci as indicators of lake Michigan recreational water quality: Comparison of two methodologies and their impacts on public health regulatory events. Appl. Environ. Microbiol., 69 (1), 92–96 (5 pages).
Lee, J. Y.; Cheon, J. Y.; Lee, K. K.; Lee, S. Y.; Lee, M. H., (2001). Statistical evaluation of geochemical parameter distribution in a ground water system contaminated with petroleum hydrocarbons. J. Environ. Qual., 30, 1548–1563 (16 pages).
Liao, S. W.; Gau, H. S.; Lai, W. L.; Chen, J. J.; Lee, C. G., (2007). Identification of pollution of Tapeng Lagoon from neighbouring rivers using multivariate statistical method. J. Environ. Manag., 88 (2), 286–292 (7 pages).
Liu, C. W.; Lin, K. H.; Kuo, Y. M., (2003). Application of factor analysis in the assessment of groundwater quality in a Blackfoot disease area in Taiwan. Sci. Total Environ., 313(1–3), 77–89 (13 pages).
Love, D.; Hallbauer, D.; Amos, A.; Hranova, R., (2004). Factor analysis as a tool in groundwater quality management: Two southern African case studies. Phys. Chemi. Earth, 29(15–18), 1135–1143 (9 pages).
Mahvi, A. H.; Nouri, J.; Babaei, A. A.; Nabizadeh, R., (2005). Agricultural activities impact on groundwater nitrate pollution. Int. J. Environ. Sci. Tech., 2 (1), 41–47 (7 pages).
Mazlum, N.; Ozer, A.; Mazlum, S., (1999). Interpretation of water quality data by principal components analysis. Tr. J. Eng. Environ. Sci., 23, 19–26 (8 pages).
Mtethiwa, A. H.; Munyenyembe, A.; Jere, W., Nyali, E., (2008). Efficiency of oxidation ponds in wastewater treatment. Int. J. Environ. Res., 2 (2), 149–152 (4 pages).
Najafpour, S.; Alkarkhi, A. F. M.; Kadir, M. O. A.; Najafpour, G. D., (2008). Evaluation of spatial and temporal variation in river water quality. Int. J. Environ. Res., 2 (4), 349–358 (10 pages).
Niemi, G. J.; Devore, P.; Detenbeck, N.; Taylor, D.; Lima, A., (1990). Overview of case studies on recovery of aquatic systems from disturbance. Environ. Manag., 14 (5), 571–587 (17 pages).
Nouri, J.; Karbassi, A. R.; Mirkia, S., (2008). Environmental management of coastal regions in the Caspian Sea. Int. J. Environ. Sci. Tech., 5 (1), 43–52 (10 pages).
Otto, M., (1998). Multivariate methods. In: Kellner, R., Mermet, J. M., Otto, M., Widmer, H. M. (Eds.), Analytical Chemistry. WileyeVCH, Weinheim, Germany, 916.
Ouyang, Y., (2005). Application of principal component and factor analysis to evaluate surface water quality monitoring network. Water Res., 39 (12), 2621–2635 (15 pages).
Ouyang, Y.; Nkedi-Kizza, P.; Wu, Q. T.; Shinde, D.; Huang, C. H., (2006). Assessment of seasonal variations in surface water quality. Water Res., 40 (20), 3800–3810 (11 pages).
Paul, M. J.; Meyer, J. L., (2001). Streams in the urban landscape. Annu. Rev. Ecol. Syst., 32 (1), 333–365 (33 pages).
Perkins, R. G.; Underwood, G. J. C., (2000). Gradients of chlorophyll a and water chemistry along an eutrophic reservoir with determination of the limiting nutrient by in situ nutrient addition. Water Res., 34 (3), 713–724 (12 pages).
Reghunath, R.; Murthy, T. R. S.; Raghavan, B. R., (2002). The utility of multivariate statistical techniques in hydrogeochemical studies: An example from Karnataka, India. Water Res., 36 (10), 2437–2442 (6 pages).
Shrestha, S.; Kazama, F., (2007). Assessment of surface water quality using multivariate statistical techniques: A case study of the Fuji river basin, Japan. Environ. Model. Software, 22 (4), 464–475 (12 pages).
Sickman, J. O.; Zanoli, M. J.; Mann, H. L., (2007). Effects of urbanization on organic carbon loads in the Sacramento river, California. Water Resour. Res., 43, W11422, 1–15 (15 pages).
Simeonov, V.; Stratis, J. A.; Samara, C.; Zachariadis, G.; Voutsa, D.; Anthemidis, A.; Sofoniou, M.; Kouimtzis, T., (2003). Assessment of the surface water quality in Northern Greece. Water Res., 37 (17), 4119–4124 (5 pages).
Singh, K. P.; Malik, A.; Mohan, D.; Sinha, S., (2004). Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of Gomti River (India): A case study. Water Res., 38 (18), 3980–3992 (13 pages).
Singh, K. P.; Malik, A.; Sinha, S., (2005). Water quality assessment and apportionment of pollution sources of Gomti River (India) using multivariate statistical techniques: A case study. Analytica. Chimica. Acta., 538(1–2), 355–374 (20 pages).
Vega, M.; Pardo, R.; Barrado, E.; Deban, L., (1998). Assessment of seasonal and polluting effects on the quality of river water by exploratory data analysis. Water Res., 32 (12), 3581–3592 (12 pages).
Voutsa, D.; Manoli, E.; Samara, C.; Sofoniou, M.; Stratis, I., (2001). A study of surface water quality in Macedonia, Greece: Speciation of nitrogen and phosphorus. Water Air Soil Pollut., 129(1–4), 13–32 (20 pages).
Williams, R. J.; Johnson, A. C.; Smith, J. J. L.; Kanda, R., (2003). Steroid estrogen profiles along river stretches arising from sewage treatment works discharges. Environ. Sci. Tech., 37 (9), 1744–1750 (7 pages).
Wunderlin, D. A.; Diaz, M. P.; Ame, M. V.; Pesce, S. F.; Hued, A. C.; Bistoni, M. A., (2001). Pattern recognition techniques for the evaluation of patial and temporal variations in water quality. A case study: Suquia river basin (Cordoba, Argentina). Water Res., 35 (12), 2881–2894 (14 pages).
Zhang, Y.; Guo, F.; Meng, W.; Wang, X. Q., (2009). Water quality assessment and source identification of Daliao River Basin using multivariate statistical methods. Environ. Monit. Assess., 152 (1-4), 105–121 (17 pages).
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Pejman, A.H., Bidhendi, G.R.N., Karbassi, A.R. et al. Evaluation of spatial and seasonal variations in surface water quality using multivariate statistical techniques. Int. J. Environ. Sci. Technol. 6, 467–476 (2009). https://doi.org/10.1007/BF03326086
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DOI: https://doi.org/10.1007/BF03326086