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Pentacyclic triterpenoid ketones in peat from Gannan Marsh, China

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Chinese Science Bulletin

Abstract

Abundant terrigenous triterpenoid ketones and a series of hopanoid ketones were detected in a peat sample from the recent Gannan Marsh. The identifications of pentacyclic triterpenoid ketones are discussed in detail. Based on the compositional features of pentacyclic triterpenoid ketones in the sample, it is proposed that terrigenous triterpenoid kentones originate directly from organisms or are diagenetic oxidation products of their alcohols, and hopanoid ketones are formed from hopanoids (e.g. hopanoid alcohols and hopenes) by chemical and biochemical processes. These data provide evidence for the applied studies of pentacyclic triterpenoid ketones as biomarker compounds.

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References

  1. Philp, R. P., Fossil Fuel Biomarkers, Applications and Spectra, Elsevier: Amsterdam, 1985.

    Google Scholar 

  2. Shi, J. Y., Xiang, M. J., Hong, Z. Q. et al., Source and evolution of pentacyclic triterpenoids, Acta Sedimentologica Sinica (in Chinese), 1991, Supplementary Issue: 26–33.

  3. Barakat, A. D., Yen, T. F., Distribution of pentacyclic triterpenoids in Green River oil shale kerogen, Org. Geochem., 1990, 15: 299.

    Article  Google Scholar 

  4. ten Haven, H. L., Peakman, T. M., Rullkotter, J., Early diagenetic transformation of higher plant triterpenoids in deep sea sediments from Baffin Bay, Geochim. Cosmochim. Acta, 1992, 56: 2001.

    Article  Google Scholar 

  5. Logan, G. A., Eglinton, G., Biogeochemistry of the Miocene lacustrine deposit at Clarkia, northern Idaho, USA, Org. Geochem., 1994, 21: 857.

    Article  Google Scholar 

  6. Duan, Y., Wen, Q. B., Luo, B. J., The carbon isotopic composition of individual n-alkanes in marsh environment, Chinese Science Bulletin, 1996, 41: 55.

    Google Scholar 

  7. Duan, Y., Organic geochemistry of recent marine sedimends from the Nansha Sea, China, Org. Geochem., 2000, 31: 159.

    Article  Google Scholar 

  8. Budzikiewicz, B. H., Wilson, J. M., Djerassi, C., Mass spectrometry in structural and stereochemical problems (XXX)—Pentacyclic triterpenes, J. American Chemical Society, 1963, 85(22): 3688.

    Article  Google Scholar 

  9. Ourisson, G., Frontiers of organic geochemistry: Some unresolved problems, Org. Geochem., 1990, 16(1–3): 21.

    Google Scholar 

  10. Brassell, S. C., Eglinton, G., Steroids and triterpenoids in deep sea sediments as environmental and diagenetic indicators, in Advances in Organic Geochemistry (eds. BjorΦy, M., Albrecht, P., Cornford, C. et al.), 1981, Chichester: John Wiley, 1983, 684–697.

    Google Scholar 

  11. Venkatesan, M. I., Ruth, E., Kaplan, J. R., Triterpenols from sediments of Santa Monica Basin, Southern California Bight, USA, Org. Geochem., 1990, 16: 1015.

    Article  Google Scholar 

  12. Gagosian, R. B., Smith, S. O., Steroid ketones in surface sediments from the southwest African Shelf, Nature, 1979, 277: 287.

    Article  Google Scholar 

  13. Fazakerley, H., Halsall, T. G., Jones, E. R. H., The chemistry of triterpenes and related compounds, Part XXXIV: The structrue of hydroxyhopanone, J. Chem. Society, 1959, May: 1877.

  14. Bauer, P. E., Dunlap, N. K., Arseniyadis, S. et al., Synthesis of biological markers in fossil fuels(I)—17α and 17β isomers of 30-norhopane and 30-normoretane, J. Org. Chem., 1983, 48: 4493.

    Article  Google Scholar 

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Duan, Y. Pentacyclic triterpenoid ketones in peat from Gannan Marsh, China. Chin.Sci.Bull. 46, 1433–1435 (2001). https://doi.org/10.1007/BF03187024

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  • DOI: https://doi.org/10.1007/BF03187024

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