Abstract
Gyarmati's governing principle of dissipative processes is used to derive the constitutive equations in the case of reversible chemical reactions and other process — reverse process combinations. Theoretical justification of Marcelin's treatment of such processes is given.
Similar content being viewed by others
References
I. Gyarmati, Non-equilibrium Thermodynamics, Field Theory and Variational Principles, Springer, Berlin-Heidelberg-New York, 1970.
Lars Onsager, Phys. Rev.,37, 405, 1931;38, 2265, 1931.
J. Meixner, Ann. Phys., (5)43, 244, 1943; Z. Phys. Chem. (B),53, 235, 1943.
I. Prigogine, Etudes thermodynamiques des phénomènes irréversibles, Dunod, Paris; Desoer, Liège, 1947.
S. R. De Groot, Thermodynamics of Irreversible Processes North Holland, Amsterdam, 1951.
I. Gyarmati, Zh. Fiz. Khim.,39, 1489, 1965; Acta Chim. Hung.,43, 353, 1965; Z. Phys. Chem. (Leipzig),234, 371, 1967;239, 133, 1968; Ann. Phys. (Leipzig), (7)23, 353, 1969.
I. Gyarmati, Periodica Polytechnica, Chemical Engineering (Budapest),5, 321, 1961; Acta Chim. Hung.,43, 353, 1965. See also J. C. M. Li, J. Chem. Phys.,29, 747, 1958.
I. Gyarmati, Ann. Phys. (Leipzig), (7)23, 353, 1969.
I. Gyarmati, Periodica Polytechnica, Chemical Engineering, (Budapest),5, 219, 1961; I. Gyarmati and K. Oláh, Acta Chim. Hung.,35, 95, 1963.
S. Lengyel, J. Chem. Phys.,88, 1617, 1988; Z. Phys. Chem. (Leipzig),270, 577, 1989.
R. Marcelin, Communication à l'Académie des Sciences, 5 décembre 1910; J. Chim. Phys.,9, 399, 1911. See also Kohnstamm and Scheffer, Communication à l'Académie royale des Pays-Bas, 24 décembre 1910.
Author information
Authors and Affiliations
Additional information
Dedicated to Prof. I. Gyarmati on his 60th birthday
Rights and permissions
About this article
Cite this article
Lengyel, S. Reversible chemical reactions in the unified field theory of thermodynamics. Acta Physica Hungarica 66, 3–18 (1989). https://doi.org/10.1007/BF03155774
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03155774