Abstract
The infra-red and Raman spectra of ordinary and deuterated barium chloride dihydrate have been studied to throw light on the intramolecular hydrogen bonds in these two crystals. The frequencies of the stretching, bending and librational modes observed in infra-red and Raman spectra exclude the possibility of at least one of the OH.... Cl hydrogen bonds, contrary to the results of NMR and neutron diffraction studies.
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5. References
Elsken, J. V. and Robinson, D. W.Spectrochim. Acta, 1961,17, 1249.
Galy, A...Compt. Rend., 1952,235, 1504.
Gamo, I...Bull. Chem. Soc. (Japan), 1961,34, 760.
Gross, E. F. ..Hydrogen Bond, Edited by Hadzi, 1959.
Jensen, A. T...Kgl. Danske Videnskab selskab Mat. Fys. Medd., 1945,3, 22.
Karay-Szabo St. V. and Sasvari, K...Zeits. Krist., 1937,97 A, 235.
Krishnan, R. S. and Balasubramanyan, K.Proc. Ind. Acad. Sci., 1964,59A, 14.
Miller, F. A. and Wilkins, C. H.Anal. Chem., 1952,24, 1253.
Padmanabhan, V. M., Busing, W. E. and Levy, H. A.Acta Cryst., 1963,16, Suppl. 4–19.
Reid, C...J. Chem. Phys., 1959,30, 182.
Salvetti, O. and Nobili, D.Ann. Chim. (Rome), 1957,47, 99.
Saxena, B. D...Proc. Ind. Acad. Sci., 1940,11A, 229.
Silvidi, A. A. and McGrath, J. W.J. Chem. Phys., 1960,32, 924.
Takaji Noto, Hiroshi Sawada and Yoshishige SatoTanabe Seiyaku Kenkyu Nempo, 1958,3, 48.
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Communicated by Professor R. S. Krishnan,f.a.sc.
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Venkatesh, G.M., Neelakantan, P. Infra-red and raman spectra of BaCl2.2H2O and BaCl2.2D2O. Proc. Indian Acad. Sci. 64, 36–43 (1966). https://doi.org/10.1007/BF03049329
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DOI: https://doi.org/10.1007/BF03049329