Skip to main content
SpringerLink
Log in

Results of investigation of the solubility of ice and water in compressed gases

  • Review
  • Published:
High Temperature Aims and scope

Abstract

Analysis is made of the experimental data available from the literature on the solubility of ice and water in various compressed gases in a wide range of temperature and pressure. A new formula is derived that relates the equilibrium concentration xeq of steam in moist gas at preassigned temperature and pressure to the constants of the equations of state for condensed water and to the virial coefficients. This formula enables one to directly calculate the solubility of steam in compressed gas without using the previously suggested solution of the set of equations. The derived formula makes it possible to describe the entire array of experimental data in the range of parameters from 200 to 400 K and from 0.1 to 10 MPa with an error equal to or less than the experimental error

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rabinovich, V.A. and Beketov, V.G.,Moist Gases: Thermodynamic Properties, New York: Begell House, 1995.

    Google Scholar 

  2. Hyland, R.W. and Wexler, A.,J. Res. Natl. Bur. Stand. Sect. A, 1973, vol. 77, no. 1, p. 133.

    Google Scholar 

  3. Hyland, R.W.,J. Res. Natl. Bur. Stand. Sect. A, 1975, vol. 79, no. 4, p. 551.

    Google Scholar 

  4. Iomtev, M.B., Piskunov, V.G., Kadzhaev, V.L.,et al., Sistema gaz-lyod. Rastvorimost’ l’da v azote i vozdukhe v diapazone temperatur ot -50°C do -2°C i davlenii ot 0.2 MPa do 61 MPa. Tablitsy RSD-GSSSD R 88-84 (The Solubility of Ice in Nitrogen and Air in the Range of Temperatures from -50°C to -2°C and Pressures from 0.2 MPa to 61 MPa: Tables of Recommended Reference Data-State Service of Standard and Reference Data R 88-84), Moscow: VNITs MV Gosstandarta SSSR (All-Union Research Center for Standardization and Certification of Raw Materials and Substances, USSR State Committee for Standards), 1984. Available from VNIIKI (All-Union Research Inst. of Space Studies), 1984, Moscow, no. 220.

    Google Scholar 

  5. Rigby, M. and Prausnitz, J.M.,J. Phys. Chem., 1968, vol. 72, no. 1, p. 330.

    Article  Google Scholar 

  6. Namiot, A.Yu.,Rastvorimost’ gazov v vode (Solubility of Gases in Water), Moscow: Nedra, 1991.

    Google Scholar 

  7. Kosyakov, N.E., Ivchenko, B.I., and Krishtopa, P.P.,Zh. Prikl. Khim., 1977, no. 11, p. 2568.

  8. Rabinovich, V.A., Beketov, V.G., Iomtev, M.B.,et al., Sistema gaz-lyod. Rastvorimost’ l’da v vodorode v diapazone temperatur -30.0°C i davlenii 0.2.30 MPa. Tablitsy RSD-GSSSD R 348-89 (The Solubility of Ice in Hydrogen in the Range of Temperatures from -30°C to 0°C and Pressures from 0.2 MPa to 30 MPa: Tables of Recommended Reference Data-State Service of Standard and Reference Data R 348-89), Moscow: VNITs MV Gosstandarta SSSR (All-Union Research Center for Standardization and Certification of Raw Materials and Substances, USSR State Committee for Standards), 1989. Available from VNIIKI (All-Union Research Inst. of Space Studies), 1990, Moscow, no. 615.

    Google Scholar 

  9. Iomtev, M.B., Piskunov, V.G., Kadzhaev, V.L.,et al., Sistema gaz-lyod. Rastvorimost’ l’da v gelii v diapazonakh temperatur ot -50°C do -2°C i davlenii ot 1.01 MPa do 35.5 MPa. Tablitsy RSD-GSSSD R 243-87 (The Solubility of Ice in Helium in the Range of Temperatures from -50°C to -2°C and Pressures from 1.01 MPa to 35.5 MPa: Tables of Recommended Reference Data-State Service of Standard and Reference Data R 243-87), Moscow: VNITs MV Gosstandarta SSSR (All-Union Research Center for Standardization and Certification of Raw Materials and Substances, USSR State Committee for Standards), 1987. Available from VNIIKI (All-Union Research Inst. of Space Studies), 1988, Moscow, no. 451.

    Google Scholar 

  10. Iomtev, M.B., Piskunov, V.G., Kadzhaev, V.L., and Gubanova, G.P.,Sistema gaz-lyod. Rastvorimost’ Vda v azote i argone v diapazone temperatur ot-40°C do -2°C i davlenii ot 0.2 MPa do 35.5 MPa. Tablitsy RSD-GSSSD R 178-86 (The Solubility of Ice in Nitrogen and Argon in the Range of Temperatures from -40°C to -2°C and Pressures from 0.2 MPa to 35.5 MPa: Tables of Recommended Reference Data-State Service of Standard and Reference Data R 178-86), Moscow: VNITs MV Gosstandarta SSSR (All-Union Research Center for Standardization and Certification of Raw Materials and Substances, USSR State Committee for Standards), 1986. Available from VNIIKI (All-Union Research Inst. of Space Studies), 1987, Moscow, no. 340.

    Google Scholar 

  11. Coan, C.R. and King, A.D.,J Am. Chem. Soc., 1971, vol. 93, no. 8, p. 1857.

    Article  Google Scholar 

  12. Beketov, V.G., Rabinovich, V.A., and Rogovin, M.D.,Raschet termodinamicheskikh svoistv vlazhnykh gazov v oblasti parametrov ot 200 do 400 K i ot 0.1 do 10 MPa. Metodika GSSSD MR 99-93 (Analysis of the Thermodynamic Properties of Moist Gases in the Range of Parameters from 200 to 400 K and from 0.1 to 10 MPa: Procedure of the State Service of Standard and Reference Data MR 99-93), 1993. Available from VNITs SMV Gosstandarta Rossii (All-Russia Research Center for Standardization and Certification of Raw Materials and Substances, State Committee for Standards of the Russian Federation).

  13. Beketov, V.G., Rabinovich, V.A., and Rogovin, M.D.,Teplofiz. Vys. Temp., 1994, vol. 32, no. 6, p. 829 (High Temp. (Engl. transl.), vol. 32, no. 6, p. 774).

    Google Scholar 

  14. Beketov, V.G. and Rabinovich, V.A.,Inzh. Fiz. Zh., 1993, vol. 64, no. 2, p. 172.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Gubkin Russian State Oil and Gas University, Moscow, Russia

    V. G. Beketov

Authors
  1. V. G. Beketov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Beketov, V.G. Results of investigation of the solubility of ice and water in compressed gases. High Temp 38, 131–140 (2000). https://doi.org/10.1007/BF02755578

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02755578

Keywords

Search

Navigation