Skip to main content
Log in

Applicability of central atoms models to binary silicate and aluminate melts

  • Published:
Metallurgical Transactions B Aims and scope Submit manuscript

Abstract

A central atoms model is presented which reproduces the phase diagram and the activities in silicate and aluminate melts. A four energy parameter model is required for this purpose. An empirical relationship is proposed which reduces the number of energy parameters to three.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C.J.B. Finchman and F.D. Richardson:Proc. R. Soc., 1954. vol. 223, p. 40.

    Article  Google Scholar 

  2. G.W. Toop and C. S. Samis:Trans. AIME, 1962, vol. 224. pp. 878–87.

    CAS  Google Scholar 

  3. C.R. Masson, I.B. Smith, and S.G. Whiteway:Can. J. Chem., 1970, vol. 18, pp. 1456–64.

    Article  Google Scholar 

  4. D.R. Gaskell:Metall. Trans. B, 1977, vol. 8B, pp. 131–45.

    Article  CAS  Google Scholar 

  5. G.M. Frohberg, M.L. Kapoor, and G.M. Mehrotra:Arch. Eisenhüttenwes., 1974, vol. 45, pp. 213–18.

    Google Scholar 

  6. K. Niwa and T. Yokakawa:Trans. Japan Inst. Metals, 1969, vol. 10, pp. 3–7.

    Google Scholar 

  7. P.L. Lin and A.D. Pelton:Metall. Trans. B. 1979, vol. 10B, pp. 667–75.

    Article  CAS  Google Scholar 

  8. P. Sastri and A. K. Lahiri:Physics and Chemistry of Glasses, 1983, vol. 24, p. 98.

    CAS  Google Scholar 

  9. D.R. Gaskell:Can. Metall. Q., 1981, vol. 20, pp. 3–19.

    CAS  Google Scholar 

  10. C. H. P. Lupis and J. F. Elliot:Acta Metall., 1967. vol. 15, p. 265.

    Article  CAS  Google Scholar 

  11. P. Hicter. J.C. Mathieu, F. Durand, and E. Bonnier:Adv. Phys., 1967. vol. 16. p. 523.

    Article  CAS  Google Scholar 

  12. E. HsinFoo and C.H.P. Lupis:Acta Metall., 1973. vol. 21.p. 1409.

    Article  Google Scholar 

  13. B. Pascal, J.C. Mathieu, P. Hicter. P. Desre, and E. Bonnier:J. Chim. Phys.. 1971, vol. 68, p. 774.

    CAS  Google Scholar 

  14. C.H.P. Lupis H. Gave, and G. Bernard:Scripta Metall.. 1970, vol. 4, pp. 497–502.

    Article  Google Scholar 

  15. E. A. Guggenheim:Mixtures, Clarendon Press. Oxford, 1952.

    Google Scholar 

  16. P. Sastri: Ph.D. Thesis. Indian Institute of Science, Bangalore, India, 1983, p. 102.

  17. J. Chipman: InPhysical Chemistry of Processes Metallurgy, G. R. St. Pierre, ed., Interscience Publishers. New York, NY. 1962, p. 42.

    Google Scholar 

  18. D.R. Gaskell:Metall. Trans., 1974, vol. 5. p. 776.

    Article  CAS  Google Scholar 

  19. W.J. Rankin:Metall. Trans. B, 1978. vol. 9B, p. 726.

    CAS  Google Scholar 

  20. R. Schumann and J. Ensio:Journal of Metals, 1951. vol. 3, p. 401.

    Google Scholar 

  21. D.R. Gaskell: personal communication. March 16. 1982.

  22. Z. Kozuka. O. P. Siahaan. and J. Moriyama:Trans. Jap. Inst. of Met., 1968, vol. 9. p. 252.

    Google Scholar 

  23. A. E. Grau and S. N. Flengas:J. Electrochem. Soc., 1967, vol. 123, p. 852.

    Article  Google Scholar 

  24. Z. Kozuka and C.S. Samis:Metall. Trans., 1970. vol. 1. p. 781.

    Google Scholar 

  25. R. J. Charles:J. Amer. Ceram. Soc., 1967, vol. 50, p. 631.

    Article  CAS  Google Scholar 

  26. J. F. Elliot, M. Glieser. and V. Ramakrishna:Thermochemistry for Steelmaking. Addison Wesley Publishing Co., Inc., Reading, NY, 1963.

    Google Scholar 

  27. S. Bannon, M. Gomez, M. Allibert. and C. Chatillon: inProc. Conf. Physical Chemistry and Steelmaking. Societé Française de Metallurgie. Paris, France, 1980, p. 242.

    Google Scholar 

  28. P. Sastri and A. K. Lahiri: unpublished research, 1984.

  29. F.D. Richardson and L.E. Webb:Bull. Inst. Min. Metall., 1955, vol. 584, p. 529.

    CAS  Google Scholar 

  30. T. Østovold and O.J. Kleppa:Inorg. Chem., 1969. vol. 8, p. 78.

    Article  Google Scholar 

  31. M. Rey: inThe Physical Chemistry of Melts, Institute of Mining and Metallurgy. 1953, p. 63.

  32. B.K.D. P. Rao and D.R. Gaskell:Metall. Trans. B, 1981, vol. 12B, p. 311.

    Article  CAS  Google Scholar 

  33. G. Urabin, Y. Bottinga, and P. Richet:Geochimica et Cosmochimica Acta. 1982. vol. 46, p. 1061.

    Article  Google Scholar 

  34. I. Kushiro: inPhysics of Magmatic Process. R. Hargraves, ed., Princeton University Press. NJ, 1980. p. 93.

    Google Scholar 

  35. Y. Bottinga and P. Richet:Earth and Planetary Science Letters, 1978, vol. 40, p. 382.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

P. Sastri, Formerly Research Student, Department of Metallurgy. Indian Institute of Science, Bangalore 560 012, India

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sastri, P., Lahiri, A.K. Applicability of central atoms models to binary silicate and aluminate melts. Metall Trans B 16, 325–331 (1985). https://doi.org/10.1007/BF02679723

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02679723

Keywords

Navigation