Abstract
A central atoms model is presented which reproduces the phase diagram and the activities in silicate and aluminate melts. A four energy parameter model is required for this purpose. An empirical relationship is proposed which reduces the number of energy parameters to three.
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C.J.B. Finchman and F.D. Richardson:Proc. R. Soc., 1954. vol. 223, p. 40.
G.W. Toop and C. S. Samis:Trans. AIME, 1962, vol. 224. pp. 878–87.
C.R. Masson, I.B. Smith, and S.G. Whiteway:Can. J. Chem., 1970, vol. 18, pp. 1456–64.
D.R. Gaskell:Metall. Trans. B, 1977, vol. 8B, pp. 131–45.
G.M. Frohberg, M.L. Kapoor, and G.M. Mehrotra:Arch. Eisenhüttenwes., 1974, vol. 45, pp. 213–18.
K. Niwa and T. Yokakawa:Trans. Japan Inst. Metals, 1969, vol. 10, pp. 3–7.
P.L. Lin and A.D. Pelton:Metall. Trans. B. 1979, vol. 10B, pp. 667–75.
P. Sastri and A. K. Lahiri:Physics and Chemistry of Glasses, 1983, vol. 24, p. 98.
D.R. Gaskell:Can. Metall. Q., 1981, vol. 20, pp. 3–19.
C. H. P. Lupis and J. F. Elliot:Acta Metall., 1967. vol. 15, p. 265.
P. Hicter. J.C. Mathieu, F. Durand, and E. Bonnier:Adv. Phys., 1967. vol. 16. p. 523.
E. HsinFoo and C.H.P. Lupis:Acta Metall., 1973. vol. 21.p. 1409.
B. Pascal, J.C. Mathieu, P. Hicter. P. Desre, and E. Bonnier:J. Chim. Phys.. 1971, vol. 68, p. 774.
C.H.P. Lupis H. Gave, and G. Bernard:Scripta Metall.. 1970, vol. 4, pp. 497–502.
E. A. Guggenheim:Mixtures, Clarendon Press. Oxford, 1952.
P. Sastri: Ph.D. Thesis. Indian Institute of Science, Bangalore, India, 1983, p. 102.
J. Chipman: InPhysical Chemistry of Processes Metallurgy, G. R. St. Pierre, ed., Interscience Publishers. New York, NY. 1962, p. 42.
D.R. Gaskell:Metall. Trans., 1974, vol. 5. p. 776.
W.J. Rankin:Metall. Trans. B, 1978. vol. 9B, p. 726.
R. Schumann and J. Ensio:Journal of Metals, 1951. vol. 3, p. 401.
D.R. Gaskell: personal communication. March 16. 1982.
Z. Kozuka. O. P. Siahaan. and J. Moriyama:Trans. Jap. Inst. of Met., 1968, vol. 9. p. 252.
A. E. Grau and S. N. Flengas:J. Electrochem. Soc., 1967, vol. 123, p. 852.
Z. Kozuka and C.S. Samis:Metall. Trans., 1970. vol. 1. p. 781.
R. J. Charles:J. Amer. Ceram. Soc., 1967, vol. 50, p. 631.
J. F. Elliot, M. Glieser. and V. Ramakrishna:Thermochemistry for Steelmaking. Addison Wesley Publishing Co., Inc., Reading, NY, 1963.
S. Bannon, M. Gomez, M. Allibert. and C. Chatillon: inProc. Conf. Physical Chemistry and Steelmaking. Societé Française de Metallurgie. Paris, France, 1980, p. 242.
P. Sastri and A. K. Lahiri: unpublished research, 1984.
F.D. Richardson and L.E. Webb:Bull. Inst. Min. Metall., 1955, vol. 584, p. 529.
T. Østovold and O.J. Kleppa:Inorg. Chem., 1969. vol. 8, p. 78.
M. Rey: inThe Physical Chemistry of Melts, Institute of Mining and Metallurgy. 1953, p. 63.
B.K.D. P. Rao and D.R. Gaskell:Metall. Trans. B, 1981, vol. 12B, p. 311.
G. Urabin, Y. Bottinga, and P. Richet:Geochimica et Cosmochimica Acta. 1982. vol. 46, p. 1061.
I. Kushiro: inPhysics of Magmatic Process. R. Hargraves, ed., Princeton University Press. NJ, 1980. p. 93.
Y. Bottinga and P. Richet:Earth and Planetary Science Letters, 1978, vol. 40, p. 382.
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P. Sastri, Formerly Research Student, Department of Metallurgy. Indian Institute of Science, Bangalore 560 012, India
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Sastri, P., Lahiri, A.K. Applicability of central atoms models to binary silicate and aluminate melts. Metall Trans B 16, 325–331 (1985). https://doi.org/10.1007/BF02679723
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DOI: https://doi.org/10.1007/BF02679723