Abstract
In the present paper, the tracer diffusivity of Si31 was measured in CaO-SiO2 melts at 1600°C. The Si31 isotope was produced by neutron bombardment in a nuclear reactor, and the capillary technique was used in the diffusion experiments. The diffusivities obtained, decrease with increasing silica content, and are lower by approximately one order of magnitude than the diffusivity of Ca45 determined previously.
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H. Keller, K. Schwerdtfeger, and K. Hennesen:Met. Trans. B, 1979, vol. 10B, pp. 67–70.
H. Towers and J. Chipman:Trans. AIME, 1957, vol. 209, pp. 769–73.
B. Langanke and H. Schmalzried: Personal communication, Institut für Physikalische Chemie, Technische Universität Hannover: H. Keller, B. Langanke, H. Schmalzried, and K. Schwerdtfeger: Preprints of the Second Japan-Germany Seminar, Tokyo, The Iron and Steel Institute of Japan, April 1976.
J. O’M. Bockris, J. D. Mackenzie, and J. A. Kitchener:Trans. Faraday Soc, 1955, vol. 51, pp. 1734–48.
C. R. Masson:J. Iron Steel Inst, 1972, pp. 89–96.
P. J. Koros and T. B. King:Trans. TMS-AIME, 1962, vol. 224, pp. 299–306.
H. Ueda and Y. Oishi:Asahi Garasu Kogyo Gijutsu Shoreikai Kenkyu Hokoku, 1970, vol. 16, pp. 201–20.
T. Saito, Y. Shiraishi, N. Nishiyama, K. Sorimachi, and Y. Sawada:The Fourth Japan-USSR Joint Symposium on Physical Chemistry of Metallurgi-cal Processes, pp. 53–65, The Iron and Steel Inst. of Japan, 1973.
J. CM. Bockris, J. A. Kitchener, and A. E. Davies:Trans. Faraday Soc, 1952, vol. 48, pp. 536–48.
O. A. Esin and A. K. Kirianov:Izv. Akad. Nauk SSSR, Otd. Tekh. Nauk, 1955, no. 12, pp. 34–38.
L. Yang and G. Derge:Physical Chemistry of Process Metallurgy, Part 1, Section V, vol. 7, pp. 503–21, Met. Soc. Aime Conf., 1959.
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Keller, H., Schwerdtfeger, K. Tracer diffusivity of Si31 in CaO-SiO2 melts at 1600°C. Metall Trans B 10, 551–554 (1979). https://doi.org/10.1007/BF02662556
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DOI: https://doi.org/10.1007/BF02662556