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Study of catalysts for the synthesis of ammonia based on lamellar compounds of graphite with ferric chloride and potassium by gamma-resonace spectroscopy method

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Together with α-iron, when the lamellar compound of graphite with FeCl3 is treated with excess potassium metal another form of iron is formed, whose isomeric shift depends on the atomic ratio of K∶Fe.

  2. 2.

    The theory was expressed that this form of iron is negatively charged and is responsible for the catalytic synthesis of ammonia.

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Authors
  1. A. V. Nefed'ev
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  2. R. A. Stukan
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  3. V. A. Postnikov
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  4. V. B. Shur
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  5. Yu. N. Novikov
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  6. M. E. Vol'pin
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Additional information

Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2376–2378, October, 1976.

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Nefed'ev, A.V., Stukan, R.A., Postnikov, V.A. et al. Study of catalysts for the synthesis of ammonia based on lamellar compounds of graphite with ferric chloride and potassium by gamma-resonace spectroscopy method. Russ Chem Bull 25, 2219–2221 (1976). https://doi.org/10.1007/BF02659559

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  • DOI: https://doi.org/10.1007/BF02659559

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